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Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b02481
Abstract: An unprecedented acid- and ligand-controlled divergent allylation of indoles with unactivated skipped enynes via Pd hydride catalysis has been disclosed. This redox-neutral transformation went through multiple hydropalladation insertion, β-hydrogen elimination, π-σ-π isomerization, and allylic substitution…
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Keywords:
catalyzed allylation;
skipped enynes;
controllable catalyzed;
indolenines allylindoles ... See more keywords