Controllable Selective Oxidation of Anilines to Azoxybenzenes and Nitrobenzenes by Regulating the Base
Sign Up to like & getrecommendations! Published in 2024 at "ACS Omega"
DOI: 10.1021/acsomega.4c04820
Abstract: The importance of selectively oxidizing aniline into value-added chemicals azoxybenzene and nitrobenzene is well-recognized in organic synthesis. However, the lack of control over selectivity and the complex synthesis of costly catalysts significantly hinder these reactions'… read more here.
Keywords: controllable selective; synthesis; base; oxidation anilines ... See more keywords
Controllable Z/E-selective synthesis of α-amino-ketoximes from N-nitrososulfonamides and aryl alkenes under neutral conditions
Sign Up to like & getrecommendations! Published in 2021 at "Organic Chemistry Frontiers"
DOI: 10.1039/d1qo01101d
Abstract: An amidoximation of alkenes with N-nitrososulfonamides enabled by triplet energy transfer under neutral conditions is presented. Both (Z)- and (E)-α-amino-ketoximes are selectively accessible depending on the triplet energy of the photosensitizer. read more here.
Keywords: selective synthesis; synthesis amino; neutral conditions; amino ketoximes ... See more keywords