Synthesis of a well-defined polyelectrolyte by controlled/“living” nitroxide-mediated radical polymerization. Kinetic study
Sign Up to like & getrecommendations! Published in 2020 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2020.109815
Abstract: Abstract The synthesis and characterization of potassium 4-styrenesulfonyl (trifluoromethylsulfonyl) imide (STFSIK) monomer as well as its controlled/living nitroxide-mediated radical polymerization (NMRP), using N-tert-Butyl-N-(2-methyl-1-phenylpropyl)-O-(1-phenylethyl) hydroxylamine as initiator in 50% w/v solutions of DMF at 125 °C, are… read more here.
Keywords: polymerization; controlled living; radical polymerization; living nitroxide ... See more keywords
Design and synthesis of trivalent Tn glycoconjugate polymers by nitroxide-mediated polymerization
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2019.130776
Abstract: Abstract A new synthetic method for preparing Tn glycoconjugate polymers, containing tumor-associated carbohydrate antigens, by controlled living radical polymerization is reported. To mimic the authentic structures of Tn glycopeptide antigens and to explore the controlled… read more here.
Keywords: polymerization; controlled living; glycoconjugate polymers; mediated polymerization ... See more keywords
Controlled Living Cascade Polymerization of Polycyclic Enyne Monomers: Leveraging Complete Degradability for a Stereochemical and Structural Investigation.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c05721
Abstract: Cascade polymerizations recently gained significant attention due to their use of unique transformations, involving multiple bond making and/or breaking steps, when converting monomers to repeat units. However, designing complex cascade polymerizations which proceed in a… read more here.
Keywords: cascade polymerization; cascade; enyne monomers; polycyclic enyne ... See more keywords