Controlled oxyanionic polymerization of propylene oxide: unlocking the molecular-weight limitation by a soft nucleophilic catalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200424
Abstract: The oxyanionic ring-opening polymerization of propylene oxide (PO) from an exogenous alcohol activated with benign (complexed) metal-alkali carboxylates is described. We demonstrate that the equimolar mixture of potassium acetate (KOAc) and 18-crown-6 ether (18C6) is… read more here.
Keywords: oxyanionic polymerization; propylene oxide; polymerization propylene; controlled oxyanionic ... See more keywords