Boron-Based Lewis Pairs Catalyzed Living, Regioselective and Topology-Controlled Polymerization of (E, E)-alkyl Sorbates.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200088
Abstract: It remains as a great challenge to realize living and controlled polymerization of renewable monomers by the boron-based Lewis pairs. Here we employ strong nucleophilic N-heterocyclic olefins (NHOs) or N-heterocyclic carbenes (NHCs) as Lewis bases… read more here.
Keywords: topology; alkyl sorbates; boron based; polymerization alkyl ... See more keywords
Controlled polymerization of styrene in the presence of Blatter’s radicals
Sign Up to like & getrecommendations! Published in 2020 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-020-2925-1
Abstract: Controlled polymerization of styrene (both self-initiated and initiated with azobisisobutyronitrile) in the presence of Blatter’s radical at 125 °C was studied. When using the radical initiator, there is no induction period. On the basis of… read more here.
Keywords: presence blatter; polymerization; controlled polymerization; polymerization styrene ... See more keywords
Rational Design of Photocatalysts for Controlled Polymerization: Effect of Structures on Photocatalytic Activities.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.1c00409
Abstract: Over the past decade, the use of photocatalysts (PCs) in controlled polymerization has brought new opportunities in sophisticated macromolecular synthesis. However, the selection of PCs in these systems has been typically based on laborious trial-and-error… read more here.
Keywords: design photocatalysts; structure property; design; controlled polymerization ... See more keywords
Reversed Controlled Polymerization (RCP): Depolymerization from Well-Defined Polymers to Monomers
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c00589
Abstract: Controlled polymerization methods are well-established synthetic protocols for the design and preparation of polymeric materials with a high degree of precision over molar mass and architecture. Exciting recent work has shown that the high end-group… read more here.
Keywords: depolymerization; polymerization rcp; reversed controlled; controlled polymerization ... See more keywords
(Controlled) Free radical (co)polymerization of multivinyl monomers: strategies, topological structures and biomedical applications.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00250k
Abstract: Free radical (co)polymerization (FRP/FRcP) of multivinyl monomers (MVMs) has emerged as a powerful strategy for the synthesis of chemically and topologically complex polymers due to its unique reaction kinetics, which enables the preparation of polymers… read more here.
Keywords: radical polymerization; free radical; controlled polymerization; multivinyl monomers ... See more keywords
Phosphonium Ylide/Organoaluminum-Based Lewis Pairs for the Highly Efficient Living/Controlled Polymerization of Alkyl (Meth)acrylates
Sign Up to like & getrecommendations! Published in 2023 at "Polymer Chemistry"
DOI: 10.1039/d3py00301a
Abstract: The development of living/controlled polymerization technologies is of great interest in both fundamental study and industrial application. Herein, we report on the use of easily synthesized phosphonium ylides Ph3P=CR1R2 (R1,R2... read more here.
Keywords: ylide organoaluminum; phosphonium ylide; living controlled; controlled polymerization ... See more keywords
Controlling Molecular Aggregation-Induced Emission by Controlled Polymerization
Sign Up to like & getrecommendations! Published in 2021 at "Molecules"
DOI: 10.3390/molecules26206267
Abstract: In last twenty years, the significant development of AIE materials has been witnessed. A number of small molecules, polymers and composites with AIE activity have been synthesized, with some of these exhibiting great potential in… read more here.
Keywords: polymerization; controlling molecular; molecular aggregation; aggregation induced ... See more keywords
Lignin Biopolymers in the Age of Controlled Polymerization
Sign Up to like & getrecommendations! Published in 2019 at "Polymers"
DOI: 10.3390/polym11071176
Abstract: Polymers made from natural biomass are gaining interest due to the rising environmental concerns and depletion of petrochemical resources. Lignin isolated from lignocellulosic biomass is the second most abundant natural polymer next to cellulose. The… read more here.
Keywords: biopolymers age; lignin biopolymers; lignin; age controlled ... See more keywords