Role of redox-inactive metals in controlling the redox potential of heterometallic manganese–oxido clusters
Sign Up to like & getrecommendations! Published in 2021 at "Photosynthesis Research"
DOI: 10.1007/s11120-021-00846-y
Abstract: Photosystem II (PSII) contains Ca2+, which is essential to the oxygen-evolving activity of the catalytic Mn4CaO5 complex. Replacement of Ca2+ with other redox-inactive metals results in a loss/decrease of oxygen-evolving activity. To investigate the role… read more here.
Keywords: inactive metals; controlling redox; redox inactive; role redox ... See more keywords
Bipolar Nanoimpact Transients: Controlling the Redox Potential ofNanoparticles in Solution
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c03316
Abstract: In the bulk solution phase the electrical potential of a single metallic nanoparticle can be controlled by its local chemical environment. In this work it is demonstrated how this nanoparticle “red... read more here.
Keywords: bipolar nanoimpact; nanoimpact transients; redox potential; solution ... See more keywords
Controlling Ni redox states by dynamic ligand exchange for electroreductive Csp3–Csp2 coupling
Sign Up to like & getrecommendations! Published in 2022 at "Science"
DOI: 10.1126/science.abo0039
Abstract: Cross-electrophile coupling (XEC) reactions of aryl and alkyl electrophiles are appealing but limited to specific substrate classes. Here, we report electroreductive XEC of previously incompatible electrophiles including tertiary alkyl bromides, aryl chlorides, and aryl/vinyl triflates.… read more here.
Keywords: carbon; controlling redox; electrochemistry; ligand exchange ... See more keywords