Homologation of halostannanes with carbenoids: a convenient and straightforward one-step access to α-functionalized organotin reagents.
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DOI: 10.1039/c8cc04786c
Abstract: A direct, single synthetic homologative transformation of halostannanes into mono- or di-substituted methyl analogues is documented. Critical for the success of the operation is the excellent nucleophilicity of carbenoid-like methyllithium reagents (LiCHXY, X, Y =… read more here.
Keywords: straightforward one; homologation halostannanes; carbenoids convenient; homologation ... See more keywords