Advanced X‐ray Absorption Spectroscopy Analysis to Determine Structure‐Activity Relationships for Cu‐Zeolites in the Direct Conversion of Methane to Methanol
Sign Up to like & getrecommendations! Published in 2020 at "ChemCatChem"
DOI: 10.1002/cctc.201902371
Abstract: An industrial process for direct conversion of methane to methanol (DMTM) would revolutionize methane as feedstock for the chemical industry and it would be a cherished contribution to climate change mitigation. At the present stage,… read more here.
Keywords: methane methanol; conversion; direct conversion; spectroscopy ... See more keywords
Systems Metabolic Engineering of Methanotrophic Bacteria for Biological Conversion of Methane to Value-Added Compounds.
Sign Up to like & getrecommendations! Published in 2022 at "Advances in biochemical engineering/biotechnology"
DOI: 10.1007/10_2021_184
Abstract: Methane is considered the carbon source with the highest potential in industrial biotechnology because of its abundance and sustainability. The biological conversion of methane into chemicals or fuels can not only reduce greenhouse gas emissions,… read more here.
Keywords: conversion methane; systems metabolic; engineering; methane ... See more keywords
Radical-initiated oxidative conversion of methane to methanol over metallic iron and copper catalysts
Sign Up to like & getrecommendations! Published in 2018 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2017.12.001
Abstract: Abstract Oxidative conversion of methane gas into value-added chemicals such as methanol is of great interest due to high economic feasibility of liquid fuel molecules for storage and transportation purpose. Activation and conversion of methane… read more here.
Keywords: methane methanol; oxidative conversion; conversion; methane ... See more keywords
Nonoxidative Direct Conversion of Methane on Silica-Based Iron Catalysts: Effect of Catalytic Surface
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DOI: 10.1021/acscatal.9b01643
Abstract: For a stable methane to olefins, aromatics, and hydrogen (MTOAH) reaction, 0.27–0.43 wt % Fe-containing silica catalysts were synthesized through various preparation methods and tested. The presence of Fe species in SiO2 mixtures increased the… read more here.
Keywords: conversion methane; nonoxidative direct; surface; methane ... See more keywords
Direct Nonoxidative Conversion of Methane to Higher Hydrocarbons over Silica-Supported Nickel Phosphide Catalyst
Sign Up to like & getrecommendations! Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b03955
Abstract: The direct dehydrogenative conversion of methane (DCM) to higher hydrocarbons has attracted much attention, because of the efficient utilization of natural gas. Ni catalysis of activation of C–H bo... read more here.
Keywords: nonoxidative conversion; direct nonoxidative; higher hydrocarbons; conversion methane ... See more keywords
Pd-Modified ZnO-Au Enabling Alkoxy Intermediates Formation and Dehydrogenation for Photocatalytic Conversion of Methane to Ethylene.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c10369
Abstract: Photocatalysis provides an intriguing approach for the conversion of methane to multicarbon (C2+) compounds under mild conditions; however, with methyl radicals as the sole reaction intermediate, the current C2+ products are dominated by ethane, with… read more here.
Keywords: dehydrogenation; methane ethylene; conversion; methane ... See more keywords
Activation and Conversion of Methane to Syngas over ZrO2/Cu(111) Catalysts near Room Temperature.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c01980
Abstract: Enzymatic systems achieve the catalytic conversion of methane at room temperature under mild conditions. In this study, varying thermodynamic and kinetic parameters, we show that the reforming of methane by water (MWR, CH4 + H2O… read more here.
Keywords: methane; room temperature; conversion methane; zro2 111 ... See more keywords
Biological conversion of methane to methanol through genetic reassembly of native catalytic domains
Sign Up to like & getrecommendations! Published in 2019 at "Nature Catalysis"
DOI: 10.1038/s41929-019-0255-1
Abstract: Methane monooxygenase (MMO), which exists in particulate (pMMO) or soluble forms (sMMO) in methanotrophic bacteria, is an industrially promising enzyme that catalyses oxidation of low-reactive methane and other carbon feedstocks into methanol and their corresponding… read more here.
Keywords: methane methanol; methanol; methane; mmo ... See more keywords
Conversion of methane to ethylene using an Ir complex and phosphorus ylide as a methylene transfer reagent.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c8cc08761j
Abstract: Cp*(Me3P)Ir(CH3)(OTf), a complex known to reversibly activate CH4 and other hydrocarbons under mild conditions, reacts with the phosphorus ylide H2CPPh3 in THF to afford two major species [Cp*(Me3P)(Ph3P)Ir(CH2CH3)][OTf] and [Cp*(Me3P)Ir(H)(η2-CH2CH2)][OTf]. Insertion of the ylide methylene… read more here.
Keywords: methane ethylene; phosphorus ylide; ylide methylene; conversion methane ... See more keywords
Reaction condition optimization for non-oxidative conversion of methane using artificial intelligence
Sign Up to like & getrecommendations! Published in 2021 at "Reaction Chemistry and Engineering"
DOI: 10.1039/d0re00378f
Abstract: Using machine learning and metaheuristic optimization, we optimize the reaction conditions for non-oxidative conversion of methane. read more here.
Keywords: non oxidative; oxidative conversion; optimization; reaction ... See more keywords
Direct conversion of methane to methanol on boron nitride-supported copper single atoms.
Sign Up to like & getrecommendations! Published in 2022 at "Nanoscale"
DOI: 10.1039/d1nr08466f
Abstract: Direct conversion of methane to methanol (DMTM) under mild conditions is one of the most attractive and challenging processes in catalysis. By using density functional theory calculations, we systematically investigate the catalytic performance of Cu… read more here.
Keywords: single atoms; conversion methane; methane methanol; direct conversion ... See more keywords