Unravelling a general mechanism of converting ionic B/N complexes into neutral B/N analogues of alkanes: Hδ+Hδ- dihydrogen bonding assisted dehydrogenation.
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DOI: 10.1039/c9cc07133d
Abstract: Long-sought mechanisms for the conversion of diammoniate of diborane ([NH3BH2NH3]+[BH4]-) into NH3BH3 and [NH2BH2]n as well as ammonium aminodiborane ([NH4]+[BH3NH2BH3]-) into a butane analogue, NH3BH2NH2BH3, have been elucidated on the basis of extensive experimental and… read more here.
Keywords: converting ionic; mechanism converting; complexes neutral; general mechanism ... See more keywords