Cooperative Activation of CO2 and Epoxide by a Heterobinuclear Al-Fe Complex via Radical Pair Mechanisms.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c13108
Abstract: Activation of inert molecules like CO2 is often mediated by cooperative chemistry between two reactive sites within a catalytic assembly, the most common form of which is Lewis acid/base bifunctionality observed in both natural metalloenzymes… read more here.
Keywords: radical pair; cooperative activation; heterobinuclear complex; activation co2 ... See more keywords
Recent advances in cooperative activation of CO2 and N2O by bimetallic coordination complexes or binuclear reaction pathways.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00210h
Abstract: The gaseous small molecules, CO2 and N2O, play important roles in climate change and ozone layer depletion, and they hold promise as underutilized reagents and chemical feedstocks. However, productive transformations of these heteroallenes are difficult… read more here.
Keywords: activation co2; co2 n2o; recent advances; cooperative activation ... See more keywords