Cooperative Si–H Addition to Side-On Ni(0)-Imine Complexes Forms Reactive Hydrosilazane Complexes
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00059
Abstract: Activation of a Si–H bond is commonly a critical step in catalytic hydrosilylation reactions. Herein, we investigate the cooperative reactivity of Ni(0) centers bearing a side-bound imine ligand toward silanes. Such complexes activate a Si–H… read more here.
Keywords: addition; imine; bond; addition side ... See more keywords