Unconventional DNA-relevant π-stacked hydrogen bonded arrays involving supramolecular guest benzoate dimers and cooperative anion–π/π–π/π–anion contacts in coordination compounds of Co(ii) and Zn(ii) phenanthroline: experimental and theoretical studies
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DOI: 10.1039/c9nj05727g
Abstract: Two new coordination compounds, viz., [Co(phen)(bz)(H2O)3]·bz (1) and [Zn(phen)2(H2O)Cl]·Cl·bzH·2H2O (2) (phen = 1,10-phenanthroline, bz = benzoate, bzH = benzoic acid) were synthesized from purely aqueous media, and characterized using elemental analysis, spectroscopic (IR, UV-Vis-NIR) and… read more here.
Keywords: coordination compounds; anion; anion anion; dna relevant ... See more keywords