Progress in metal-free cooperative catalysis for the ring-opening copolymerization of cyclic anhydrides and epoxides
Sign Up to like & getrecommendations! Published in 2019 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2019.109276
Abstract: Abstract Recent progress in the design of metal-free Lewis pair catalysts indicates a bright future for the synthesis of various polyesters with broad applications. In the present review, we attempt to highlight the recent advancements… read more here.
Keywords: cooperative catalysis; ring opening; cyclic anhydrides; free cooperative ... See more keywords
Cross-coupling reactions by cooperative Pd/Cu or Ni/Cu catalysis based on the catalytic generation of organocopper nucleophiles
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2018.12.013
Abstract: Abstract In this review, cross-coupling reactions by cooperative Pd/Cu or Ni/Cu catalysis based on catalytically generated organocopper nucleophiles are summarized. Compared to conventional methods based on the use of stoichiometric amounts of pre-synthesized organometallic reagents,… read more here.
Keywords: cross coupling; catalysis based; organocopper nucleophiles; cooperative catalysis ... See more keywords
Palladium/Norbornene Cooperative Catalysis.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.9b00079
Abstract: Palladium/norbornene cooperative catalysis has emerged as a distinct approach to construct polyfunctionalized arenes from readily available starting materials. This Review provides a comprehensive overview of this field, including the early stoichiometric investigations, catalytic reaction developments,… read more here.
Keywords: palladium norbornene; norbornene cooperative; cooperative catalysis;
Catalytic Asymmetric Umpolung Tandem Reactions of Hemiacetals via Dinuclear Zinc Cooperative Catalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00913
Abstract: The umpolung activity of hemiacetals serving as α-carbon nucleophiles has been reported via dinuclear zinc cooperative catalysis. This umpolung strategy has been applied to catalytic asymmetric tandem reactions of 1-tosylindoline-2,3-diols with β,γ-unsaturated-α-keto compounds, providing a… read more here.
Keywords: dinuclear zinc; tandem reactions; cooperative catalysis; via dinuclear ... See more keywords
Intramolecularly Cooperative Catalysis for Copolymerization of Cyclic Thioanhydrides and Epoxides: A Dual Activation Strategy to Well-Defined Polythioesters
Sign Up to like & getrecommendations! Published in 2020 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c00906
Abstract: The copolymerization of epoxides and cyclic thioanhydrides provides a promising method to produce polythioesters and represents an alternative route to the step-growth condensation of dithiols and ... read more here.
Keywords: cooperative catalysis; intramolecularly cooperative; catalysis copolymerization; copolymerization ... See more keywords
Cooperative Pd/Cu Catalysis for Alkene Arylboration: Opportunities for Divergent Reactivity.
Sign Up to like & getrecommendations! Published in 2022 at "ACS catalysis"
DOI: 10.1021/acscatal.1c05696
Abstract: A preeminent challenge in alkene difunctionalization is the control of regio-, diastereo-, and enantioselectivity. In this Perspective, a Pd/Cu-cooperative catalytic system for alkene arylboration is highlighted that allows for the controlled introduction of substituents. In… read more here.
Keywords: cooperative catalysis; alkene arylboration; divergent reactivity;
Cooperative Catalysis: A Strategy To Synthesize Trifluoromethyl-thioesters from Aldehydes
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b01519
Abstract: A cooperative catalysis between a photoredox and a hydrogen atom transfer (HAT) catalyst has been developed to synthesize trifluoromethylthioesters from aldehydes. This reaction is mild, highly selective, operationally simple, works under redox neutral condition, and… read more here.
Keywords: cooperative catalysis; strategy synthesize; catalysis strategy; synthesize trifluoromethyl ... See more keywords
Models for Cooperative Catalysis: Oxidative Addition Reactions of Dimethylplatinum(II) Complexes with Ligands Having Both NH and OH Functionality
Sign Up to like & getrecommendations! Published in 2019 at "ACS Omega"
DOI: 10.1021/acsomega.8b03089
Abstract: The role of NH and OH groups in the oxidative addition reactions of the complexes [PtMe2(κ2-N,N′-L)], L = 2-C5H4NCH2NH-x-C6H4OH [3, x = 2, L = L1; 4, x = 3, L = L2; 5, x… read more here.
Keywords: models cooperative; cooperative catalysis; oxidative addition; addition reactions ... See more keywords
Structurally Modified Norbornenes: A Key Factor to Modulate Reaction Selectivity in the Palladium/Norbornene Cooperative Catalysis.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c09193
Abstract: Palladium/norbornene (Pd/NBE) cooperative catalysis has received enormous attention and found numerous synthetic applications in the past two decades. Considering the critical roles that NBE plays in the catalytic cycle, the use of structurally modified NBEs… read more here.
Keywords: cooperative catalysis; modulate reaction; palladium norbornene; catalysis ... See more keywords
Synthesis of discrete catalytic oligomers and their potential in silica-supported cooperative catalysis
Sign Up to like & getrecommendations! Published in 2019 at "RSC Advances"
DOI: 10.1039/c9ra00847k
Abstract: The synthesis of discrete catalytic oligomers and their potential in supported cooperative catalysis are presented. read more here.
Keywords: catalytic oligomers; cooperative catalysis; oligomers potential; supported cooperative ... See more keywords
Cooperative catalysis of Zn3(VO4)2/Ni(OH)2/rGO nanosheet arrays advancing highly active O2 reduction and water-splitting
Sign Up to like & getrecommendations! Published in 2023 at "New Journal of Chemistry"
DOI: 10.1039/d3nj00907f
Abstract: Electrocatalytic O2 conversion and water-splitting hold great promise to enable the chemicals-electricity inter-transition in many renewable-energy initiatives. Enhancing the kinetics of oxygen reduction reaction (ORR) is challenging. Here, we present... read more here.
Keywords: cooperative catalysis; water; water splitting; zn3 vo4 ... See more keywords