Cooperative CO2 Scission by Anomalous Insertion into a Rh–Si Bond
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DOI: 10.1021/acs.organomet.9b00556
Abstract: Pincer-type [P2Si]Rh complexes featuring a rhodium–silicon bond are shown to facilitate well-defined stoichiometric reductions of CO2 with Si–O bond formation by two different pathways: (a) hydride transfer to CO2 followed by formate migration to silicon,… read more here.
Keywords: bond; co2; cooperative co2; anomalous insertion ... See more keywords