Enhanced Chelate Cooperativity in Polar Solvents.
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DOI: 10.1021/jacs.7b01765
Abstract: High-throughput UV-vis titrations in combination with chemical double-mutant cycles (DMCs) have been used to study the competition of a polar solvent for formation of intramolecular H-bonds. Twenty-four different zinc porphyrin-pyridine complexes were investigated in mixtures… read more here.
Keywords: chelate cooperativity; phenol; cooperativity polar; polar solvents ... See more keywords