Magnetic anisotropy and slow magnetic relaxation of seven-coordinate cobalt(II)–nitrate complexes
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.07.050
Abstract: Abstract Two seven-coordinate cobalt(II) complexes with the molecular formulae [Co(L)(NO3)2(CH3CN)] (L = 2,2′-bipyridine, 1; L = 1,10-phenanthroline, 2) were prepared and magnetically characterized. X-ray single crystal diffraction shows that 1 exhibit the distorted pentagonal bipyramidal geometry around the central… read more here.
Keywords: coordinate cobalt; seven coordinate; slow magnetic; magnetic relaxation ... See more keywords
Reactivity of a Two-Coordinate Cobalt(0) Cyclic (Alkyl)(amino)carbene Complex
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DOI: 10.1021/acs.organomet.9b00875
Abstract: Cyclic (alkyl)(amino)carbenes (cAACs) are the merely known ligand set being capable of stabilizing two-coordinate cobalt(0) complexes. While two complexes of the type [(R2-cAAC)2Co] [R2-cAAC = 5,5-... read more here.
Keywords: coordinate cobalt; two coordinate; reactivity two; alkyl amino ... See more keywords