A cyanide-bridged wheel featuring a seven-coordinate Mo(iii) center.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c8cc09373c
Abstract: A new cyclic molecule incorporating [MoIII(CN)7]4- has been characterized by single crystal X-ray methods, SQUID magnetometry and theoretical calculations. The wheel molecule [MoIII(CN)7]6[Ni(L)]12(H2O)6 exhibits ferromagnetic Mo-Ni coupling which did not exist for the previously reported… read more here.
Keywords: bridged wheel; wheel featuring; cyanide bridged; seven coordinate ... See more keywords
Tuning the ligand field in seven-coordinate Dy(iii) complexes to perturb single-ion magnet behavior
Sign Up to like & getrecommendations! Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d1nj00734c
Abstract: Two mononuclear seven-coordinate Dy(iii) complexes with different strengths of ligand fields exhibit different slow magnetic relaxations. read more here.
Keywords: iii complexes; coordinate iii; seven coordinate; tuning ligand ... See more keywords