Bioinorganic supramolecular coordination complexes and their biomedical applications
Sign Up to like & getrecommendations! Published in 2022 at "FEBS Letters"
DOI: 10.1002/1873-3468.14535
Abstract: The field of Bioinorganic Supramolecular Chemistry is an emerging research area including metal‐based supramolecules resulting from coordination‐driven self‐assembly (CDSA), whereby metal ions and organic ligands can be easily linked by metal–ligand bonds via Lewis' acid/base… read more here.
Keywords: coordination complexes; bioinorganic supramolecular; coordination; biomedical applications ... See more keywords
Elucidating the Coordination of Diethyl Sulfide Molecules in Copper(I) Thiocyanate (CuSCN) Thin Films and Improving Hole Transport by Antisolvent Treatment
Sign Up to like & getrecommendations! Published in 2020 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202002355
Abstract: Copper(I) thiocyanate (CuSCN) is rising to prominence as a hole‐transporting semiconductor in various opto/electronic applications. Its unique combination of good hole mobility, high optical transparency, and solution‐processability renders it a promising hole‐transport layer for solar… read more here.
Keywords: copper thiocyanate; thiocyanate cuscn; coordination; treatment ... See more keywords
Regulating the Electronic Configuration of Ni Sites by Breaking Symmetry of Ni‐Porphyrin to Facilitate CO2 Photocatalytic Reduction
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202316199
Abstract: Adapting the coordination environment to influence the electronic configuration of active sites represents an efficient approach for improving the photocatalytic performance of the CO2 reduction reaction (CO2RR) but how to execute it precisely remains challenging.… read more here.
Keywords: co2; symmetry; reduction; electronic configuration ... See more keywords
Strong Tough Ionic Organohydrogels with Negative‐Thermopower via the Synergy of Coordination Interaction and Hofmeister Effect
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202406968
Abstract: Ionic thermoelectric (i‐TE) gels have attracted widespread attention in flexible electronics due to their flexibility, leakage‐free, low toxicity, and converting low‐grade waste heat into electricity. For practical application, it is strongly desirable to fabricate negative‐thermopower… read more here.
Keywords: via synergy; hofmeister effect; negative thermopower; synergy coordination ... See more keywords
Tailoring Coordination Fields of Asymmetric MO5S1‐Type Metal–Organic Frameworks Catalysts for Accelerated Oxygen Evolution Reaction
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202413856
Abstract: Asymmetric coordination has emerged as a promising approach to enhance the oxygen evolution reaction (OER) activity, yet achieving a controlled synthesis of asymmetric structures to comprehensively understand the structure‐activity relationship remains challenging. In this study,… read more here.
Keywords: reaction; evolution reaction; asymmetric mo5s1; mo5s1 type ... See more keywords
Spin Regulation of Nickel Single Atom Catalyst via Axial Phosphor‐Coordination Achieves Near Unity CO Selectivity in Electrochemical CO2 Reduction
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202419989
Abstract: The engineering of the spin state and axial coordination of the metal center of single‐atom catalyst (SAC) represents an effective strategy for regulating the catalytic activity, selectivity, and stability toward electrocatalytic reduction of CO2 (ECO2R).… read more here.
Keywords: near unity; co2; selectivity; single atom ... See more keywords
Tailoring Highly Ion‐Conductive and Stabled PVDF‐Based Solid Electrolyte via Surface Coordination Chemistry
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202422461
Abstract: The composite solid‐state electrolyte, composed of polyvinylidene fluoride (PVDF) polymer and garnet, exhibits great promising in solid‐state batteries. However, the dehydrofluorination of PVDF induced by the garnet narrows its voltage window and deteriorates the electrode‐electrolyte… read more here.
Keywords: chemistry; surface; electrolyte; solid state ... See more keywords
Coordination‐Induced Plastic Ceramic‐Ether Coupling Electrolyte for High‐Voltage Lithium Metal Batteries
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202506241
Abstract: The high‐voltage reactivity and flammability of electrolytes remain critical challenges for high‐safety and high‐energy‐density lithium metal batteries (LMBs). Here, a novel ceramic‐ether coupling electrolyte (CCE) is reported, in which a thin liquid layer of the… read more here.
Keywords: lithium metal; metal batteries; voltage; ceramic ether ... See more keywords
Flexibility and Dynamicity Enhances and Controls Supramolecular Self‐Assembly of Zinc(II) Metallogels
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202507793
Abstract: Supramolecular self‐assembly of stacked architectures is typically achieved through hydrogen bonding or π–π interactions between monomers constructed from stable and inert bonds. In contrast, coordinative interactions of early metals promise distinct self‐assembly behaviour due to… read more here.
Keywords: chemistry; supramolecular self; dynamicity; self assembly ... See more keywords
Tethering Transition Metals of Li‐Rich Manganese Oxides via Anion Coordination for High‐Voltage Lithium‐Metal Batteries
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202514328
Abstract: Transition metal (TM) ions dissolution from lithium‐rich manganese oxides (LRMO) cathode is positioned to the central factor to widen the upper voltage and prolong cycle life. While a body of research documents elemental doping or… read more here.
Keywords: chemistry; manganese oxides; cation anion; anion ... See more keywords
Switchable, Recyclable, and Time‐Programmable Hydrogels via Counterion‐Engineered Differential Metal‐Ion Coordination
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202514481
Abstract: Multifunctional hydrogels applied in flexible electronics and smart sensing face prominent challenges including functionality integration, environmental adaptability, and sustainability. This paper presents an anti‐ion‐regulated differential metal‐ion coordination strategy to fabricate a multifunctional hydrogel (SP‐Mn+Xy−) with… read more here.
Keywords: time; differential metal; metal ion; ion ... See more keywords