Bioinorganic supramolecular coordination complexes and their biomedical applications
Sign Up to like & getrecommendations! Published in 2022 at "FEBS Letters"
DOI: 10.1002/1873-3468.14535
Abstract: The field of Bioinorganic Supramolecular Chemistry is an emerging research area including metal‐based supramolecules resulting from coordination‐driven self‐assembly (CDSA), whereby metal ions and organic ligands can be easily linked by metal–ligand bonds via Lewis' acid/base… read more here.
Keywords: coordination complexes; bioinorganic supramolecular; coordination; biomedical applications ... See more keywords
Elucidating the Coordination of Diethyl Sulfide Molecules in Copper(I) Thiocyanate (CuSCN) Thin Films and Improving Hole Transport by Antisolvent Treatment
Sign Up to like & getrecommendations! Published in 2020 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202002355
Abstract: Copper(I) thiocyanate (CuSCN) is rising to prominence as a hole‐transporting semiconductor in various opto/electronic applications. Its unique combination of good hole mobility, high optical transparency, and solution‐processability renders it a promising hole‐transport layer for solar… read more here.
Keywords: copper thiocyanate; thiocyanate cuscn; coordination; treatment ... See more keywords
Moldable Hyaluronan Hydrogel Enabled by Dynamic Metal-Bisphosphonate Coordination Chemistry for Wound Healing.
Sign Up to like & getrecommendations! Published in 2018 at "Advanced healthcare materials"
DOI: 10.1002/adhm.201700973
Abstract: Biomaterial-based regenerative approaches would allow for cost-effective off-the-shelf solution for the treatment of wounds. Hyaluronan (HA)-based hydrogel is one attractive biomaterial candidate because it is involved in natural healing processes, including inflammation, granulation, and reepithelialization.… read more here.
Keywords: wound healing; coordination; dynamic metal; chemistry ... See more keywords
Coordination‐Driven Metal‐Polyphenolic Nanoparticles toward Effective Anticancer Therapy
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DOI: 10.1002/adhm.202200559
Abstract: Stabilization of bioactive components, especially for hydrophobic functional factors, is a promising approach for improving their biological activity. Here, a metal‐phenolic coordination chemistry that synthesizes biocompatible and biodegradable thin film based on tannic acid and… read more here.
Keywords: coordination; metal polyphenolic; therapy; coordination driven ... See more keywords
Materials Design of Solar Cell Absorbers Beyond Perovskites and Conventional Semiconductors via Combining Tetrahedral and Octahedral Coordination.
Sign Up to like & getrecommendations! Published in 2019 at "Advanced materials"
DOI: 10.1002/adma.201806593
Abstract: Tetrahedral coordination structures, e.g. crystalline Si, GaAs, CdTe, and octahedral coordination structures, e.g. perovskites, represent two classes of successful crystal structures hitherto for solar cell absorbers. Here, via first-principles calculations and crystal symmetry analysis, the… read more here.
Keywords: octahedral coordination; coordination; tetrahedral octahedral; cell absorbers ... See more keywords
Sulfuration of Li‐Rich Mn‐Based Cathode Materials for Multianionic Redox and Stabilized Coordination Environment
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DOI: 10.1002/adma.202109564
Abstract: Lithium‐rich transition metal oxides (LLOs) can deliver high specific capacity over 250 mAh g−1, stemming from additional contribution of oxygen redox. However, the formation of O(2−n)− (0 < n < 2) species and even oxygen… read more here.
Keywords: multianionic redox; sulfuration rich; coordination; redox ... See more keywords
Ultrastable Fe–N–C Fuel Cell Electrocatalysts by Eliminating Non‐Coordinating Nitrogen and Regulating Coordination Structures at High Temperatures
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202204474
Abstract: Pyrolyzed Fe–N–C materials have attracted considerable interest as one of the most active noble‐metal‐free electrocatalysts for the oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs). Despite significant progress is made in improving… read more here.
Keywords: fuel cell; coordination; fuel; stability ... See more keywords
Regulating the Coordination Environment of Mesopore‐Confined Single Atoms from Metalloprotein‐MOFs for Highly Efficient Biocatalysis
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202205674
Abstract: Single‐atom catalysts (SACs) exhibit unparalleled atomic utilization and catalytic efficiency, yet it is challenging to modulate SACs with highly dispersed single‐atoms, mesopores, and well‐regulated coordination environment simultaneously and ultimately maximize their catalytic efficiency. Here, a… read more here.
Keywords: single atoms; sacs; coordination; highly efficient ... See more keywords
Coordination Symmetry Breaking of Single‐Atom Catalysts for Robust and Efficient Nitrate Electroreduction to Ammonia
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DOI: 10.1002/adma.202205767
Abstract: Nitrate electrocatalytic reduction (NO3RR) for ammonia production is a promising strategy to close the N‐cycle from nitration contamination, as well as an alternative to the Haber–Bosch process with less energy consumption and carbon dioxide release.… read more here.
Keywords: coordination symmetry; coordination; symmetry breaking; atom catalysts ... See more keywords
Coordination Polymer Electrocatalysts Enable Efficient CO‐to‐Acetate Conversion
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DOI: 10.1002/adma.202209567
Abstract: Upgrading carbon dioxide/monoxide to multi‐carbon C2+ products using renewable electricity offers one route to more sustainable fuel and chemical production. One of the most appealing products is acetate, the profitable electrosynthesis of which demands a… read more here.
Keywords: acetate conversion; coordination; coordination polymer;
Conjugated Coordination Polymer as a New Platform for Efficient and Selective Electroreduction of Nitrate into Ammonia
Sign Up to like & getrecommendations! Published in 2023 at "Advanced Materials"
DOI: 10.1002/adma.202209855
Abstract: Electroreduction of nitrate into ammonia (NRA) provides a sustainable route to convert the widespread nitrate pollutants into high‐value‐added products under ambient conditions, which unfortunately suffers from unsatisfactory selectivity due to the competitive hydrogen evolution reaction… read more here.
Keywords: coordination; conjugated coordination; nitrate ammonia; electroreduction nitrate ... See more keywords