Introducing two-dimensional metal-organic frameworks with axial coordination anion into Pebax for CO2/CH4 separation
Sign Up to like & getrecommendations! Published in 2020 at "Separation and Purification Technology"
DOI: 10.1016/j.seppur.2020.118107
Abstract: Abstract Two-dimensional (2D) MOF named Cu(BPY)2(OTF)2 (OTF = trifluoromethanesulfonic acid anion (CF3SO3−), BPY = 4,4-bipyridine) possessing axial coordination anion was prepared, and then combined into Pebax® MH 1657 (Pebax) polymer to fabricate mixed matrix membranes (MMMs) for the separation… read more here.
Keywords: anion; pebax; bpy otf; coordination anion ... See more keywords
Coordination anion effects on the geometry and magnetic interaction of binuclear Dy2 single-molecule magnets.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt02071d
Abstract: Two new dimeric dysprosium(III) complexes, [Dy2(HL)2(SCN)2]·2CH3CN (1) and [Dy2(HL)2(NO3)2]·2CH3CN·2H2O (2), have been assembled using the H3L multidentate ligand (H3L = 2,2'-((((2-hydroxy-5-methyl-1,3-phenylene)bis(methylene))bis((pyridin-2-ylmethyl)azanediyl))bis(methylene))diphenol). The use of different coordination anions for the two complexes results in distinct coordination… read more here.
Keywords: coordination; single molecule; anion effects; coordination anion ... See more keywords