Distinctive coordination behavior of a pyrazole imine-oxime compound towards Co(II) and Ni(II)
Sign Up to like & getrecommendations! Published in 2019 at "Heliyon"
DOI: 10.1016/j.heliyon.2019.e01623
Abstract: The polytopic Schiff base 5-methyl-1H-pyrazole-3-carboxylic acid 2-(hydroxyimino-1-methyl-propylidene)-hydrazide (H2L)was synthesized by the condensation of 5-methyl pyrazole-3-carbohydrazide and 3-(hydroxyimino)butan-2-one and its coordination ability was tested against cobalt (II) and nickel (II) nitrates. The ligand exhibited two different… read more here.
Keywords: methyl; coordination; distinctive coordination; coordination behavior ... See more keywords
Unexpected coordination behavior of ruthenium to a polymeric α-diimine containing the poly[bis(arylimino)acenaphthene] fragment
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2021.120257
Abstract: Abstract Use of homogeneous catalysts poses the problem of their recovery at the end of the reaction. A possible strategy to circumvent this problem is to make the ligand part of a polymer with limited… read more here.
Keywords: coordination behavior; ruthenium; coordination; oligo bian ... See more keywords
Coordination behavior of new bis(tridentate ONO, ONS and ONN) donor hydrazones towards some transition metal ions: Synthesis, spectral, thermal, antimicrobial and antitumor studies
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2016.08.056
Abstract: Abstract Three new hydrazone ligands, H 2 L 1 , H 2 L 2 and H 4 L 3 , were prepared by condensation of 4,6-bis(1-hydrazonoethyl)benzene-1,3-diol with furan-2-carboxaldehyde, thiophene-2-carboxaldehyde and 1H-pyrrole-2-carboxaldehyde, respectively. The ligands reacted… read more here.
Keywords: coordination behavior; new bis; behavior new; metal ... See more keywords
Coordination behavior of 1-(3,2′:6′,3″-terpyridin-4′-yl)ferrocene: Structure and magnetic and electrochemical properties of a tetracopper dimetallomacrocycle
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2017.03.030
Abstract: Abstract The discrete coordination compound [Cu4Cl8(3)4(MeOH)2] is obtained from the reaction of a chloroform solution of 1-(3,2′:6′,3″-terpyridin-4′-yl)ferrocene (3) with a methanol solution of CuCl2; the single crystal structure of [{Cu4Cl8(3)4(MeOH)2}·0.7CHCl3·1.8MeOH] is described. Two {Cu2Cl4(3)2(MeOH)} units… read more here.
Keywords: terpyridin ferrocene; coordination; coordination behavior; structure ... See more keywords
Effect of Internal Ligand Strain on Coordination Behavior of PSP Pincer Ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03044
Abstract: Chelating ligands and most specifically pincer ligands, with their characteristic co-planar binding, usually undergo deformations upon coordination, resulting in a significant ligand strain. Such an effect on the properties of the so formed complex has… read more here.
Keywords: pincer; coordination; ligand; strain ... See more keywords
Quo vadis niobium? Divergent coordination behavior of early-transition metals towards MOF-5† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc01553a
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Science"
DOI: 10.1039/c9sc01553a
Abstract: Despite its prevalence, cation exchange is not the only immobilization pathway for foreign cations in the epochal MOF-5 metal–organic framework. read more here.
Keywords: coordination behavior; niobium divergent; quo vadis; divergent coordination ... See more keywords