An interlocked coordination cage based on aromatic amide ligands
Sign Up to like & getrecommendations! Published in 2020 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2020.11.002
Abstract: Abstract An interlocked M4L8 coordination cage was synthesized by coordination-driven self-assembly of palladium(II) ions with aromatic amide bidentate ligands. The reaction of the ligand and the metal at 2:1 ratio led to the monomeric M2L4… read more here.
Keywords: coordination; aromatic amide; coordination cage; interlocked coordination ... See more keywords
A Charged Coordination Cage-Based Porous Salt.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c02806
Abstract: Metal-organic frameworks and porous coordination cages have shown incredible promise as a result of their high tunability. However, syntheses pursuing precisely targeted mixed functionalities, such as multiple ligand types or mixed-metal compositions are often serendipitous,… read more here.
Keywords: cage; charged coordination; coordination cage; porous salt ... See more keywords
Modulating the Optical Properties of BODIPY Dyes by Noncovalent Dimerization within a Flexible Coordination Cage
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c08589
Abstract: Aggregation of organic molecules can drastically affect their physicochemical properties. For instance, the optical properties of BODIPY dyes are inherently related to the degree of aggregation and the mutual orientation of BODIPY units within these… read more here.
Keywords: coordination cage; properties bodipy; optical properties; bodipy dyes ... See more keywords
Uranyl dication mediated photoswitching of a calix[4]pyrrole-based metal coordination cage.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc05160g
Abstract: A set of self-assembled tri- and tetrapodal metal coordination cage structures (cage-1 and cage-2, respectively) constructed from the uranyl dication (UO22+) and a dibenzoic acid functionalised cis-calix[4]pyrrole (1) are described. The inherent photochemical reactivity of… read more here.
Keywords: coordination cage; calix pyrrole; uranyl dication; cage ... See more keywords
Bimolecular proximity of a ruthenium complex and methylene blue within an anionic porous coordination cage for enhancing photocatalytic activity††Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05315d
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Science"
DOI: 10.1039/c8sc05315d
Abstract: An anionic coordination cage encapsulates the catalyst and the substrate within its cavity, circumvent the charge repulsion, thus promotes the activity in the photocatalysis. read more here.
Keywords: bimolecular proximity; coordination; proximity ruthenium; coordination cage ... See more keywords
Outside the box: quantifying interactions of anions with the exterior surface of a cationic coordination cage.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d0dt04211k
Abstract: We describe a study of the binding of anions to the surface of an octanuclear coordination cage HW, which carries a 16+ charge, in aqueous solution. Anionic aromatic fluorophores such as fluorescein (and derivatives) and… read more here.
Keywords: outside box; coordination cage; box quantifying; cage ... See more keywords
Orthogonal binding and displacement of different guest types using a coordination cage host with cavity-based and surface-based binding sites
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Science"
DOI: 10.1039/d1sc04272f
Abstract: The octanuclear Co(ii) cubic coordination cage system H (or HW if it bears external water-solubilising substituents) has two types of binding site for guests. These are (i) the partially-enclosed central cavity where neutral hydrophobic organic… read more here.
Keywords: coordination cage; surface; cavity; guest ... See more keywords