Coordination cages in catalysis
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Inclusion Phenomena and Macrocyclic Chemistry"
DOI: 10.1007/s10847-019-00964-0
Abstract: Catalysis is an important process across multiple disciplines, and there are still many challenges to be met. Enzymes, “nature’s catalysts”, display impressive efficacy with controlled selectivity and rapid throughput, so attempting to mimic these properties… read more here.
Keywords: coordination cages; coordination; cages catalysis; chemistry ... See more keywords
Catalysis within coordination cages
Sign Up to like & getrecommendations! Published in 2020 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2020.213656
Abstract: Abstract Coordination cages with well-defined cavities have attracted sustained attention for their applications in many fields, including host-guest chemistry, molecular recognition, and catalysis, due to their structural aesthetics and unique properties. This review covers the… read more here.
Keywords: coordination; cages catalysis; chemistry; coordination cages ... See more keywords
Cation-Anion Arrangement Patterns in Self-Assembled Pd2L4 and Pd4L8 Coordination Cages.
Sign Up to like & getrecommendations! Published in 2017 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.7b00231
Abstract: Compounds featuring one-dimensional regular arrangements of stacked metal complexes and alternating [cation-anion]∞ sequences have raised considerable interest owing to their peculiar electronic and optical properties as well as guest inclusion capabilities. While traditional ways to… read more here.
Keywords: cation anion; metal; coordination cages; coordination ... See more keywords
Utilization of a Mixed-Ligand Strategy to Tune the Properties of Cuboctahedral Porous Coordination Cages.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03519
Abstract: Ligand functionalization has been thoroughly leveraged to alter the properties of paddlewheel-based coordination cages where, in the case of ligand-terminated cages, functional groups are positioned on the periphery of synthesized cages. While these groups can… read more here.
Keywords: functional groups; ligand; coordination cages; strategy ... See more keywords
Toward Coordination Cages with Hybrid Chirality: Amino Acid-Induced Chirality on Metal Centers
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c01738
Abstract: Tripodal chiral ligands containing amino acid residues and salicyl-acylhydrazone units were synthesized and used to obtain coordination cages through deprotonation and coordination to gallium. These coordination cages have Ga3L2 stoichiometry and pinwheel geometry with two… read more here.
Keywords: geometry; coordination cages; amino acid; chirality ... See more keywords
Rhenium(I)-Based Neutral Coordination Cages with a Spherical Cavity for Selective Recognition of Fluoride.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02408
Abstract: Neutral heteroleptic trinuclear coordination cages containing a preorganized well-defined small spherical endocavity, which is made up of electron-deficient bowl frameworks, three coordination-induced neutral polar C-H donors, and a phenyl motif, were self-assembled via a one-pot… read more here.
Keywords: neutral coordination; based neutral; coordination; coordination cages ... See more keywords
Embedding of Functionalized Coordination Cages and a Molecular Knot in a Polymeric Membrane for Potentiometric Sensing of Environmentally Important Oxyanions and Halides.
Sign Up to like & getrecommendations! Published in 2022 at "ACS sensors"
DOI: 10.1021/acssensors.2c00782
Abstract: Three kinds of coordination cages and a molecular knot with inductively activated +P-H, N-H, or C-H hydrogen bond donors anchoring in the functionalized cavities were inspected as ionophores to develop polymeric membrane ISEs for potentiometric… read more here.
Keywords: molecular knot; potentiometric sensing; cages molecular; coordination cages ... See more keywords
Light-Powered Dissipative Assembly of Diazocine Coordination Cages
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c12011
Abstract: Stimuli-responsive coordination cages allow reversible control over guest binding and release, relevant for adaptive receptors, carriers, catalysts, and complex systems. Light serves as an advantageous stimulus, as it can be applied with precise spatial and… read more here.
Keywords: powered dissipative; coordination; coordination cages; dissipative assembly ... See more keywords
Methane Storage in Paddlewheel-Based Porous Coordination Cages.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b05780
Abstract: Although gas adsorption properties of extended three-dimensional metal-organic materials have been widely studied, they remain relatively unexplored in porous molecular systems. This is particularly the case for porous coordination cages for which surface areas are… read more here.
Keywords: coordination; paddlewheel based; methane storage; porous coordination ... See more keywords
Otherwise Unstable Structures Self-Assemble in the Cavities of Cuboctahedral Coordination Cages.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b07494
Abstract: We present a method for the directed self-assembly of interlocked structures and coordination complexes in a set of metal-organic hosts. New homo- and heteroleptic metal complexes-species that cannot be prepared outside-form within the cavities of… read more here.
Keywords: cuboctahedral coordination; unstable structures; coordination; otherwise unstable ... See more keywords
Chiral supramolecular coordination cages as high-performance inhibitors against amyloid-β aggregation.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc04913k
Abstract: Four pairs of chiral supramolecular coordination cages were facilely synthesized, and they could efficiently inhibit amyloid-β (Aβ) aggregation with a high inhibition rate of 0.64-0.86. This research provides a new perspective on the design of… read more here.
Keywords: coordination cages; chiral supramolecular; amyloid aggregation; supramolecular coordination ... See more keywords