Polynuclear ampyrone based 3d coordination clusters
Sign Up to like & getrecommendations! Published in 2018 at "CrystEngComm"
DOI: 10.1039/c7ce02093g
Abstract: The use of the monoanionic Schiff base ligand (E)-4-(2-hydroxybenzylideneamino)-2,3-dimethyl-1-phenyl-1,2-dihydropyrazol-5-one in transition (Co, Ni and Cu) coordination chemistry yields mono-, tetra- and pentanuclear coordination clusters (CCs) with different structural motifs. An organic transformation occurs in the… read more here.
Keywords: polynuclear ampyrone; coordination; coordination clusters; ampyrone based ... See more keywords
Targeted replacement: systematic studies of dodecanuclear {MLn} coordination clusters (M = Cr, Co; Ln = Dy, Y).
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt01289j
Abstract: Three dodecanuclear 3d-4f coordination clusters, [CrIII6LnIII6(μ3-OH)8(tbdea)6(C6H5COO)16]·2H2O (Ln = Dy (1), Y (2)) and [CoIII6DyIII6(μ3-OH)8(nbdea)6(m-CH3C6H4COO)16]·2H2O·2CH3CN (3), have been synthesized under solvothermal conditions and characterized. Single-crystal X-ray diffraction analysis revealed that all three compounds possess an analogous… read more here.
Keywords: coordination; coordination clusters; replacement systematic; targeted replacement ... See more keywords