Nonanuclear coordination complex based on {Co9L12}6+ cores: protective effect on coronary heart disease by reducing the inflammatory cytokines releasing
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Papers"
DOI: 10.1007/s11696-020-01390-0
Abstract: A new coordination complex with the chemical formula of [Co9(bta)12(NO3)6(DMA)6]·3DMA (1), (DMA = N,N-dimethylacetamide) was formed by solvothermal reaction of Co(NO3)2·6H2O with Hbta (Hbta = benzotriazole). The as-prepared complex 1 was characterized via thermogravimetric (TG) analysis, analysis of element,… read more here.
Keywords: inflammatory cytokines; heart disease; coordination complex;
A heterotrinuclear bioinspired coordination complex capable of binding to DNA and emulation of nuclease activity.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2021.111631
Abstract: The investigation of compounds capable of strongly and selectively interacting with DNA comprises a field of research in constant development. In this work, we demonstrate that a trinuclear coordination complex based on a dinuclear Fe(III)Zn(II)… read more here.
Keywords: dna; heterotrinuclear bioinspired; complex; coordination complex ... See more keywords
Hydrothermal synthesis, crystal structure, luminescent and magnetic properties of a new mononuclear Gd III coordination complex
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2018.02.089
Abstract: Abstract A new GdIII coordination complex, {[Gd(2-stp)2(H2O)6].2(4,4'-bipy).4(H2O)}, complex 1, (2-stp = 2-sulfoterephthalate anion and 4,4'-bipy = 4,4'-bipyridine), has been synthesized by hydrothermal method and characterized by elemental analysis, solid state UV–Vis and FT-IR spectroscopy, single-crystal X-ray diffraction, solid state… read more here.
Keywords: bipy; crystal structure; coordination complex; structure ... See more keywords
Excellent catalytic activity of ethylenediamine stabilised oxalate ligated aluminium coordination complex for synthesis of novel benzoquinolines
Sign Up to like & getrecommendations! Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2020.114734
Abstract: Abstract Two-dimensional supramolecular structure of oxalate ligated Al(III) coordination complex, (C2H10N2)2.[Al2(µ-O2)(oxalate)4]∙2H2O (Al-Ox) was synthesised hydrothermally and determined the structural features with single-crystal X-ray diffraction studies. Unique oxo bridged dinuclear Al(III) clusters were established and each… read more here.
Keywords: oxalate ligated; excellent catalytic; catalytic activity; activity ... See more keywords
A Zinc Coordination Complex Mimicking Carbonic Anhydrase for CO2 Hydrolysis and Sequestration.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b01059
Abstract: Carbonic anhydrase (CA) mimicking is an effective and environmentally friendly strategy for carbon dioxide sequestration. Herein, we developed a nonanuclear CA-mimetic zinc coordination complex (1) which possesses a coordination environment similar to that of CA's… read more here.
Keywords: carbonic anhydrase; coordination; zinc coordination; zinc ... See more keywords
Visible-Light-Driven "On"/"Off" Photochromism of a Polyoxometalate Diarylethene Coordination Complex.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b04900
Abstract: Herein we report the first photochromic polyoxometalate (POM)-based diarylethene (DAE) coordination complex, prepared by ligation of two cobalt(III)-incorporated borotungstates [BIIIWVI11O39CoIII]6- with the ditopic pyridyl-containing diarylethene (C25H16N2F6S2). The solution-state composition, structure, and stability of the assembly… read more here.
Keywords: polyoxometalate; coordination; visible light; spectroscopy ... See more keywords
A bis-vanadyl coordination complex as a 2-qubit quantum gate.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/c9cc09817h
Abstract: A new bis-hydroxyphenylpyrazolyl ligand, H4L, allows isolating and structurally characterizing vanadyl and titanyl dinuclear complexes (Bu4N)2[(MO)2(HL)2] (M = V, Ti). The weak dipolar coupling and relatively short quantum coherence of the divanadyl anions are optimal… read more here.
Keywords: vanadyl coordination; complex qubit; quantum; bis vanadyl ... See more keywords
A photoluminescent Au(I)/Ag(I)/PNN coordination complex for relatively rapid and reversible alcohol sensing.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt00931a
Abstract: Trinuclear complex [Au2Ag(dppmaphen)2(CN)2]PF6 photoluminesces on exposure to low molecular weight alcohols. This emission is likely due to C-Hπ interactions between the analyte and -PPh2 group, that inhibits non-radiative relaxation of the photoexcited state. Photoluminescene was… read more here.
Keywords: relatively rapid; pnn coordination; rapid reversible; photoluminescent pnn ... See more keywords
On the non-existence of a square-planar pentaiodide coordination complex I(I)4.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02501a
Abstract: The properties of two conformers of the pentaiodide ion, a V-shaped and regularly observed I5- ion, and a so far undetected square-planar coordination complex of II4- composition, have been investigated by computational methods. The latter… read more here.
Keywords: square planar; coordination; coordination complex; non existence ... See more keywords
Conformational dynamicity in a copper(II) coordination complex.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt01213a
Abstract: The geometries of copper coordination complexes are intricately related to their electron transfer capabilities, but the role of dynamics in these processes are not fully understood. We have previously reported CuCl(dpaOMe), a complex exhibiting conformational… read more here.
Keywords: state; coordination; conformational dynamicity; coordination complex ... See more keywords
Catalytic aquathermolysis of heavy oil by coordination complex at relatively low temperature
Sign Up to like & getrecommendations! Published in 2017 at "Petroleum Chemistry"
DOI: 10.1134/s096554411710005x
Abstract: A series of Mannich base-transition metal coordination complex was synthesized and used for the catalytic aquathermolysis of heavy oil, among which we found that the Ni(II) complex is the most effective one. After reacted under… read more here.
Keywords: aquathermolysis heavy; aquathermolysis; catalytic aquathermolysis; heavy oil ... See more keywords