Articles with "coordination compound" as a keyword



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Thermal and spectroscopic analysis of Co(II)–Fe(III) polyglyoxylate obtained through the reaction of ethylene glycol with metal nitrates

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Published in 2017 at "Journal of Thermal Analysis and Calorimetry"

DOI: 10.1007/s10973-016-6079-1

Abstract: The synthesis and thermal and spectroscopic studies of a new CoII–FeIII heteropolynuclear coordination compound are presented. The in situ oxidation product of ethylene glycol plays the role of ligand. Under specific working conditions, the reaction… read more here.

Keywords: reaction ethylene; analysis; ethylene glycol; thermal spectroscopic ... See more keywords
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Mechanistic studies on the in-situ generation of furoxan ring during the formation of Cu(II) coordination compound from dioxime ligand: Theoretical and experimental study

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Published in 2020 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2020.119756

Abstract: Abstract The copper(II) coordination compound, [Cu(Lʹ)(NO3)2] (1) where Lʹ = 3,4-di(pyridin-2-yl)-1,2,5-oxadiazole 2-oxide, was synthesized from the reaction of Cu(NO3)2·3H2O and dioxime ligand, (1E,2E)-1,2-di(pyridin-2-yl)ethane-1,2-dione dioxime (L), in methanol under aerial atmosphere. The dark-blue crystals of 1… read more here.

Keywords: furoxan ring; formation; dioxime; compound ... See more keywords
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Heterobimetallic Dy-Cu coordination compound as a classical-quantum ferrimagnetic chain of regularly alternating Ising and Heisenberg spins

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Published in 2018 at "Journal of Magnetism and Magnetic Materials"

DOI: 10.1016/j.jmmm.2018.04.021

Abstract: Abstract A classical-quantum chain composed of regularly alternating Ising and Heisenberg spins is rigorously solved by considering two distinct local anisotropy axes of the Ising spins. The ground-state phase diagram and magnetization curves are examined… read more here.

Keywords: regularly alternating; coordination compound; chain; classical quantum ... See more keywords
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Synthesis and Absorption Properties of Hollow-spherical Dy2Cu2O5 via a Coordination Compound Method with [DyCu(3,4-pdc)2(OAc)(H2O)2]•10.5H2O Precursor

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Published in 2017 at "Scientific Reports"

DOI: 10.1038/s41598-017-13544-4

Abstract: Dy2Cu2O5 nanoparticles with perovskite structures were synthesized via a simple solution method (SSM) and a coordination compound method (CCM) using [DyCu(3,4-pdc)2(OAc)(H2O)2]•10.5H2O (pdc = 3,4-pyridinedicarboxylic acid) as precursor. The as-prepared samples were structurally characterized by X-ray diffraction (XRD),… read more here.

Keywords: adsorption; microscopy; method; dy2cu2o5 ... See more keywords
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Green solvent free epoxidation of olefins by a heterogenised hydrazone-dioxidotungsten(vi) coordination compound

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Published in 2022 at "RSC Advances"

DOI: 10.1039/d1ra09217k

Abstract: A new mononuclear tungsten coordination compound, [WO2L(CH3OH)] (1), was synthesized by the reaction of WCl6 and H2L (H2L = (E)-4-amino-N′-(5-bromo-2-hydroxybenzylidene)benzohydrazide) in methanol. Both the H2L and compound 1 were characterized by elemental analysis and UV-Vis,… read more here.

Keywords: coordination compound; spectroscopy; epoxidation olefins; compound ... See more keywords
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A copper(II) coordination compound under water-oxidation reaction at neutral conditions: decomposition on the counter electrode.

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Published in 2022 at "Dalton transactions"

DOI: 10.1039/d2dt01572b

Abstract: In the context of energy storage, the oxygen-evolution reaction (OER, 2H2O → O2 + 4H+ + 4e-) through the water-oxidation reaction is a thermodynamically uphill reaction in overall water splitting. In recent years, copper(II) coordination… read more here.

Keywords: reaction; coordination; water; coordination compound ... See more keywords
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Coordination compound-derived Fe4N/Fe3N/Fe/CNT for efficient electrocatalytic oxygen evolution: a facile one-step synthesis in the absence of extra nitrogen source

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Published in 2022 at "Nanotechnology"

DOI: 10.1088/1361-6528/ac810b

Abstract: By annealing an Fe(III)–coordination compound (Fe–CC), [FeCl3(Hbta)2] (Hbta = benzotriazole) in the presence of a carbon nanotube precursor (PCNT) template, an Fe4N/Fe3N/Fe/CNT heterostructure was successfully synthesized without an extra nitrogen source. The decomposition of the… read more here.

Keywords: carbon; fe3n; coordination compound; fe3n cnt ... See more keywords
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Dependence of the Fe(II)-Gallic Acid Coordination Compound Formation Constant on the pH

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Published in 2021 at "Foods"

DOI: 10.3390/foods10112689

Abstract: One important property of tannins involves their ability to form coordination compounds with metal ions, which is vital for the bioavailability of these ions, as well as for the antibacterial and antioxidative activities of tannins.… read more here.

Keywords: coordination; dependence; gallic acid; formation ... See more keywords
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Design of Research on Performance of a New Iridium Coordination Compound for the Detection of Hg2+

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Published in 2017 at "International Journal of Environmental Research and Public Health"

DOI: 10.3390/ijerph14101232

Abstract: Heavy metal pollution has become one of the most significant pollution problems encountered by our country in terms of environment protection. In addition to the significant effects of heavy metals on the human body and… read more here.

Keywords: coordination compound; coordination; detection; iridium coordination ... See more keywords