Regulating Chlorine and Hydrogen Atom Transfer for Selective Photoelectrochemical C─C Coupling by Cu‐coordination Effect at Semiconductor/Electrolyte Interfaces
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DOI: 10.1002/advs.202408767
Abstract: Semiconductor‐based photoelectrochemical (PEC) organic transformations usually show radical characteristics, in which the reaction selectivity is often difficult to precisely control due to the nonselectivity of radicals. Accordingly, several simple organic reactions (e.g., oxidations of alcohols,… read more here.
Keywords: electrolyte interfaces; effect semiconductor; semiconductor; semiconductor electrolyte ... See more keywords
Coordination effect enabled palladium-catalyzed regioselective O-alkylation of 2-pyridones.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06110k
Abstract: A novel tactic for the regioselective O-alkylation of 2-pyridones has been realized through palladium catalysis in moderate to high yields. The coordination effect between palladium and nitrogen on the pyridine ring plays a versatile role. read more here.
Keywords: regioselective alkylation; coordination effect; alkylation pyridones; palladium ... See more keywords
Titanium nitride concentration and coordination effect with hexagonal boron nitride enhancing the reciprocating wear behavior of AZ91D alloy-based composites
Sign Up to like & getrecommendations! Published in 2022 at "Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science"
DOI: 10.1177/09544062221130198
Abstract: The influence of TiN hard ceramic concentration and coordination effect of hBN solid lubricant particulates on reciprocating wear and friction behavior of AZ91D alloy-based magnesium matrix composites is investigated in this work. A unique stir-ultrasonication-squeeze… read more here.
Keywords: coordination effect; reciprocating wear; microscopy; az91d alloy ... See more keywords
Eliminating Stubborn Insulated Deposition by Coordination Effect to Boost Zn Electrode Reversibility in Aqueous Electrolyte
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2022.851973
Abstract: Aqueous rechargeable zinc-ion batteries (ZIBs) have recently shined in energy storage and transmission, which are due to high safety and low cost. However, the extremely stubborn by-products in the Zn anode severely inhibited the Zn2+… read more here.
Keywords: coordination effect; coordination; deposition; eliminating stubborn ... See more keywords