Articles with "coordination environment" as a keyword



Regulating the Coordination Environment of Mesopore‐Confined Single Atoms from Metalloprotein‐MOFs for Highly Efficient Biocatalysis

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Published in 2022 at "Advanced Materials"

DOI: 10.1002/adma.202205674

Abstract: Single‐atom catalysts (SACs) exhibit unparalleled atomic utilization and catalytic efficiency, yet it is challenging to modulate SACs with highly dispersed single‐atoms, mesopores, and well‐regulated coordination environment simultaneously and ultimately maximize their catalytic efficiency. Here, a… read more here.

Keywords: single atoms; sacs; coordination; highly efficient ... See more keywords

Tuning the Coordination Environment of Carbon-Based Single-Atom Catalysts via Doping with Multiple Heteroatoms and Their Applications in Electrocatalysis.

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Published in 2023 at "Advanced materials"

DOI: 10.1002/adma.202210575

Abstract: Carbon-based single-atom catalysts (SACs) are considered to be a perfect platform for studying the structure-activity relationship of different reactions due to the adjustability of their coordination environment. Multi-heteroatom doping has been demonstrated as an effective… read more here.

Keywords: single atom; carbon based; carbon; coordination environment ... See more keywords

Tuning Surface Coordination Environment of Ni3N by Fluorine Modification for Efficient Methanol Electrooxidation Assisted Hydrogen Evolution

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Published in 2025 at "Advanced Materials"

DOI: 10.1002/adma.202507573

Abstract: Replacing the kinetically sluggish oxygen evolution reaction with the thermodynamically favorable methanol oxidation reaction (MOR) represents a promising strategy for energy‐efficient hydrogen production. However, optimizing electrocatalytic performance in the coupled hydrogen evolution reaction (HER) and… read more here.

Keywords: coordination environment; evolution; hydrogen evolution; environment ni3n ... See more keywords

Regulation of Coordination Environment Over Cu Sites: Triggering the Efficient Selective Catalytic Reduction of NOx Using NH3 as Reductant

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Published in 2024 at "Applied Organometallic Chemistry"

DOI: 10.1002/aoc.7906

Abstract: The design of the controlled coordination environment over Cu sites for selective catalytic reduction of NOx using NH3 as reductant (NH3‐SCR) is still challenging. A series of dispersed Cu catalysts with different coordination environments were… read more here.

Keywords: temperature; coordination environment; nh3 scr; environment sites ... See more keywords

Boosting Electrocatalytic Activity of Single Atom Catalysts Supported on Nitrogen-Doped Carbon through N Coordination Environment Engineering.

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Published in 2022 at "Small"

DOI: 10.1002/smll.202105329

Abstract: Nonprecious group metal (NPGM)-based single atom catalysts (SACs) hold a great potential in electrocatalysis and dopant engineering has been extensively exploited to boost their catalytic activity, while the coordination environment of dopant, which also significantly… read more here.

Keywords: nitrogen doped; single atom; coordination environment; activity ... See more keywords

Tailoring Li+ Local Coordination Environment of Solid Polymer Electrolytes to Boom Ionic Conductivity.

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Published in 2024 at "Small"

DOI: 10.1002/smll.202407430

Abstract: The low ionic conductivity is the key issue of solid polymer electrolytes (SPEs), hampering their practical application. Great efforts have been devoted to reducing their crystallinity to increase ionic conductivity but ignored their Li+ local… read more here.

Keywords: local coordination; coordination environment; ionic conductivity; conductivity ... See more keywords

Regulating the coordination environment of Co single atoms for achieving efficient electrocatalytic activity in CO2 reduction

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Published in 2019 at "Applied Catalysis B: Environmental"

DOI: 10.1016/j.apcatb.2018.08.075

Abstract: Abstract Regulating the coordination environment of Co single-atom catalysts represents a powerful strategy to enhance its catalytic performance for CO2 electrochemical reduction. Herein, we adopt metal-organic frameworks (MOFs) to assist the preparation of Co single-atom… read more here.

Keywords: co2; coordination environment; regulating coordination; reduction ... See more keywords

Calcium coordination environment in precursor species to calcium carbonate mineral formation

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Published in 2019 at "Geochimica et Cosmochimica Acta"

DOI: 10.1016/j.gca.2019.05.041

Abstract: Abstract The local coordination environment in precursors to calcium carbonate minerals has been studied at pH 7.5 and 8.5 by use of a novel fast mixing device with a freeze quench and freeze-drying method coupled… read more here.

Keywords: calcium carbonate; coordination; coordination environment;

Oxidation state and coordination environment of Pb in U-bearing minerals

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Published in 2019 at "Geochimica et Cosmochimica Acta"

DOI: 10.1016/j.gca.2019.08.039

Abstract: Abstract This study examines the oxidation and coordination of lead (Pb) in the uranium (U) minerals uraninite (UO2), coffinite (USiO4), and brannerite (UTi2O6), and minerals that have U as a minor constituent, zircon (ZrSiO4) and… read more here.

Keywords: pb2; coordination; bearing minerals; coordination environment ... See more keywords

On the Coordination Environment of Single-Atom Catalysts.

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Published in 2025 at "Accounts of chemical research"

DOI: 10.1021/acs.accounts.5c00140

Abstract: ConspectusSingle-atom catalysis has become one of the most active frontiers in catalysis in the past decade. This concept not only gives birth to a new kind of heterogeneous catalysts featuring well-defined isolated active sites and… read more here.

Keywords: coordination environment; atom; catalysis; support ... See more keywords

Tailoring the Coordination Environment of Fe/Zn-BDC to Boost Peroxidase-like Activity for Highly Selective Detection of PFOS.

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Published in 2024 at "Analytical chemistry"

DOI: 10.1021/acs.analchem.4c00016

Abstract: Perfluorooctanesulfonic acid potassium salt (PFOS) residues in ecosystems over long periods are of increasing concern and require a selective and stable optical probe for monitoring. Herein, two functional groups (-F and -NH2) with opposite electronic… read more here.

Keywords: like activity; coordination environment; peroxidase like; bdc ... See more keywords