Statistical Analysis of Coordination Environments in Oxides
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DOI: 10.1021/acs.chemmater.7b02766
Abstract: Coordination or local environments (e.g., tetrahedra and octahedra) are powerful descriptors of the crystalline structure of materials. These structural descriptors are essential to the understanding of crystal chemistry and the design of new materials. However,… read more here.
Keywords: coordination; coordination environments; analysis coordination; chemistry ... See more keywords
The necessity of free and uncrowded coordination environments in biomimetic complex models: oxidative coupling by mixed-ligand cobalt(ii) complexes of diazene–disulfonamide
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DOI: 10.1039/c9nj04396a
Abstract: Importance of molecular access to Co(ii) site is shown by new tridentate disulfonamides, which stabilize uncommon 5-coordinate mixed-ligand vacant-octahedral geometries. read more here.
Keywords: coordination environments; necessity free; free uncrowded; mixed ligand ... See more keywords
Mechanistic insights into the formation of hydroxides with unconventional coordination environments to achieve their cost-effective synthesis
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DOI: 10.1093/nsr/nwae427
Abstract: ABSTRACT Transition metal hydroxides, comprising metal-centered polyhedra, are abundant in nature and have a broad range of applications. Although the intercalation/deintercalation of polyhedra with unconventional coordination numbers (UCN) plays a pivotal role in their formation… read more here.
Keywords: unconventional coordination; intercalation; synthesis; coordination environments ... See more keywords
Superionic lithium transport via multiple coordination environments defined by two-anion packing
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DOI: 10.1126/science.adh5115
Abstract: Fast cation transport in solids underpins energy storage. Materials design has focused on structures that can define transport pathways with minimal cation coordination change, restricting attention to a small part of chemical space. Motivated by… read more here.
Keywords: lithium; anion packing; transport; coordination environments ... See more keywords