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   Articles with "coordination induced" as a keyword



Coordination‐Induced Magnetism Strategy for Highly Selective and Efficient Uranium Separation

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recommendations! Published in 2024 at "Advanced Science"

DOI: 10.1002/advs.202408642

Abstract: Highly efficient separation of dispersed uranium is important for the sustainable development of nuclear industry, and adsorption is the most recognized approach. However, there are many coexisting interfering metal ions that compete with uranyl ion… read more here.

Keywords: induced magnetism; separation; uranium; strategy ... See more keywords

Switching Spin‐States: Spin Crossover vs. Coordination‐Induced Spin‐State Switching

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recommendations! Published in 2024 at "European Journal of Inorganic Chemistry"

DOI: 10.1002/ejic.202400471

Abstract: Switchable molecular materials have continued to attract the interest of chemists and physicists for decades. A prominent example are spin crossover complexes, where numerous textbooks, review articles, and special issues are available. A highly interesting… read more here.

Keywords: coordination induced; state switching; induced spin; spin state ... See more keywords

Coordination-Induced Bond Weakening.

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recommendations! Published in 2022 at "Chemical reviews"

DOI: 10.1021/acs.chemrev.2c00254

Abstract: Coordination-induced bond weakening is a phenomenon wherein ligand X-H bond homolysis occurs in concert with the energetically favorable oxidation of a coordinating metal complex. The coupling of these two processes enables thermodynamically favorable proton-coupled electron… read more here.

Keywords: coordination induced; bond weakening; induced bond; bond ... See more keywords
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Coordination-Induced N–H Bond Weakening in a Molybdenum Pyrrolidine Complex: Isotopic Labeling Provides Insight into the Pathway for H2 Evolution

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recommendations! Published in 2020 at "Organometallics"

DOI: 10.1021/acs.organomet.0c00471

Abstract: The synthesis and characterization of a cationic molybdenum pyrrolidine complex are described that exhibits significant coordination-induced N–H bond weakening. The N–H bond dissociation free energ... read more here.

Keywords: pyrrolidine complex; induced bond; bond; molybdenum pyrrolidine ... See more keywords

Coordination-Induced Trigger for Activity: N-Heterocyclic Carbene-Decorated Ceria Catalysts Incorporating Cr and Rh with Activity Induction by Surface Adsorption Site Control.

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recommendations! Published in 2022 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.2c07290

Abstract: A coordination-induced trigger for catalytic activity is proposed on an N-heterocyclic carbene (NHC)-decorated ceria catalyst incorporating Cr and Rh (ICy-r-Cr0.19Rh0.06CeOz). ICy-r-Cr0.19Rh0.06CeOz was prepared by grafting 1,3-dicyclohexylimidazol-2-ylidene (ICy) onto H2-reduced Cr0.19Rh0.06CeOz (r-Cr0.19Rh0.06CeOz) surfaces, which went on… read more here.

Keywords: induced trigger; 19rh0 06ceoz; coordination induced; activity ... See more keywords

Coordination-induced O-H/N-H bond weakening by a redox non-innocent, aluminum-containing radical

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recommendations! Published in 2024 at "Nature Communications"

DOI: 10.1038/s41467-024-45721-1

Abstract: Several renewable energy schemes aim to use the chemical bonds in abundant molecules like water and ammonia as energy reservoirs. Because the O-H and N-H bonds are quite strong (>100 kcal/mol), it is necessary to identify… read more here.

Keywords: induced bond; coordination induced; bond weakening; redox non ... See more keywords

Reversible coordination-induced spin-state switching in complexes on metal surfaces

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recommendations! Published in 2019 at "Nature Nanotechnology"

DOI: 10.1038/s41565-019-0594-8

Abstract: Molecular spin switches are attractive candidates for controlling the spin polarization developing at the interface between molecules and magnetic metal surfaces1,2, which is relevant for molecular spintronics devices3–5. However, so far, intrinsic spin switches such… read more here.

Keywords: functionality; metal; spin; metal surfaces ... See more keywords

Coordination-induced O-H bond weakening in Sm(ii)-water complexes.

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recommendations! Published in 2019 at "Dalton transactions"

DOI: 10.1039/c9dt03352a

Abstract: The combination of Sm(ii)-based reductants with water provides reagent systems that promote a range of reductions and bond-forming reactions that are endergonic based on known redox potentials. Despite the utility of these reagent systems, little… read more here.

Keywords: induced bond; water; bond; bond weakening ... See more keywords

Coordination-induced reductive elimination from a titanium(IV) complex.

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recommendations! Published in 2024 at "Chemical communications"

DOI: 10.1039/d4cc02500h

Abstract: Diamidopyridine-supported titanium dibenzyl complexes undergo coordination-induced C-C reductive elimination upon addition of alkynes and quantitative formation of titanacyclopentadienes. The distinct radical mechanism of this reductive mechanism gives new insights into C-C bond formation with titanium. read more here.

Keywords: reductive elimination; coordination induced; titanium; induced reductive ... See more keywords

Asymmetrical Sc coordination-induced bridging structure and surface relaxation for boosting H2O2 photoactivation in Fenton-like catalysis

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recommendations! Published in 2024 at "Journal of Materials Chemistry A"

DOI: 10.1039/d4ta05800c

Abstract: A single-atom of the transition metal scandium is introduced into the g-C3N4/MoSe2 heterojunction interfaces to form a single-atom bridging structure (Se–Sc–N) for H2O2 activation in a photo-Fenton-like system. read more here.

Keywords: coordination induced; bridging structure; fenton like; asymmetrical coordination ... See more keywords

Coordination-Induced Spin-State Memory via Cooperative binding

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recommendations! Published in 2025 at "Inorganic Chemistry Frontiers"

DOI: 10.1039/d5qi01394a

Abstract: Molecular magnetic units capable of Coordination-Induced Spin-State Switching (CISSS) are embedded within a soft porous crystal (SPC) framework, enabling cooperative and bistable spin-state memory at room temperature. The transformation between... read more here.

Keywords: induced spin; state memory; spin state; coordination induced ... See more keywords