Tuning the Coordination Microenvironment of Central Fe Active Site to Boost Water Electrolysis and Oxygen Reduction Activity.
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DOI: 10.1002/smll.202205111
Abstract: In heterogeneous catalysis, single-atom catalysts are the frontier and important prototypes for many reactions, and revealing the intrinsic structure-activity relationship is presently a critical task, but remains challenging. In this work, water electrolysis and oxygen… read more here.
Keywords: coordination; electrolysis oxygen; oxygen reduction; activity ... See more keywords
Coordination microenvironment perturbed single-ion magnet behavior in a β-diketone Dy(iii) complex
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DOI: 10.1039/d0ce00935k
Abstract: A β-diketonate mononuclear dysprosium compound, [Dy(DBM)2(bpy)(CH3OH)2]·Cl− (1) (DBM = dibenzoylmethane, bpy = 2,2′-bipyridine), has been prepared and structurally and magnetically characterized. The metal centers in 1 adopt an approximately square-antiprismatic (SAP) coordination environment with D4d… read more here.
Keywords: coordination; single ion; microenvironment perturbed; coordination microenvironment ... See more keywords
Functional Conversion of Acetyl-Coenzyme a Synthase to a Nickel Superoxide Dismutase via Rational Design of Coordination Microenvironment for the Nid-Site
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DOI: 10.3390/ijms23052652
Abstract: The Nid site coordination microenvironment of a truncated acetyl-coenzyme A synthase has been designed systematically for functional conversion to a Ni-SOD-like enzyme. To this end, the first strategy is to introduce an axial histidine ligand,… read more here.
Keywords: sod like; coordination microenvironment; f598h;