Synthetic approaches and supramolecular properties of 2,2′:n′,m″-terpyridine domains (n = 3,4,5,6; m = 2,3,4) based on the 2,2′-bipyridine core as ligands with k2N-bidentate coordination mode
Sign Up to like & getrecommendations! Published in 2021 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2021.213980
Abstract: Abstract Despite almost a century-long history of studying the potential of 2,2′:6′,2″-terpyridine in various fields, the development of synthetic atom-economic “one-pot” approaches/techniques/methods (meeting the requirements of “green chemistry”) of the “parent” 2,2′:6′,2″-tpy domain and its… read more here.
Keywords: terpyridine domains; bidentate coordination; coordination; chemistry ... See more keywords
Syntheses and structural aspects of dinuclear cycloplatinated N,N′,N″-triarylguanidinate(2−) complexes with a novel tridentate μ2-κ2(C,N):κ1N coordination mode
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121138
Abstract: Abstract Metal complexes of N-substituted guanidines are well known in the field of inorganic, organometallic chemistry, catalysis and materials chemistry. Factors that determine coordination modes of this class of N-donor ligands determine nuclearity of the… read more here.
Keywords: coordination; coordination mode; chemistry; dinuclear cycloplatinated ... See more keywords
Coordination mode of the N-[bis(diethylamino)phosphoryl]benzenesulfonamide ligand in Lu(III) and Ag(I) complexes. Mass spectra, thermal properties and DFT calculations
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DOI: 10.1016/j.poly.2017.09.038
Abstract: Abstract The sulfonylamidophosphate ligand C6H5SO2NHPO(N(C2H5)2)2 (HL) has been used for the synthesis of two novel complexes: LuL3 (1) and (AgL)n (2). According to an X-ray diffraction study, in the structure of HL, the molecules are… read more here.
Keywords: coordination mode; dft calculations; mode bis; ligand ... See more keywords
Impact of Coordination Mode and Ferrocene Functionalization on the Anticancer Activity of N-Heterocyclic Carbene Half-Sandwich Complexes.
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DOI: 10.1021/acs.inorgchem.2c02832
Abstract: The substitution of phenyl rings in established drugs with ferrocenyl moieties has been reported to yield compounds with improved biological activity and alternative modes of action, often involving the formation of reactive oxygen species (ROS).… read more here.
Keywords: coordination mode; impact coordination; activity; heterocyclic carbene ... See more keywords
Multinuclear Cu(I) Clusters Featuring a New Triply Bridging Coordination Mode of Phosphaamidinate Ligands.
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DOI: 10.1021/acs.inorgchem.8b01422
Abstract: Phosphabenzamidine [mes-NH-C(Ph)═P-mes) (1) and phosphaformamidine (mes-NH-CH═P-mes) (4) ligands have been synthesized and characterized. The conjugate bases of 1 and 4 coordinate by each bridging three Cu(I) ions, forming hexa- and tetranuclear clusters Cu6[mes-N═C(Ph)-P-mes]3Cl4Li(THF)2 (3) and… read more here.
Keywords: coordination mode; multinuclear clusters; clusters featuring; mes mes ... See more keywords
Highly flexible phosphabenzenes: a missing coordination mode of 2,4,6-triaryl-λ3-phosphinines.
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DOI: 10.1039/d2cc01817a
Abstract: The reaction of 2,4,6-triaryl-λ3-phosphinine-Cr(CO)3-π-complexes with [Rh(COD)2]BF4 leads to unusual diamagnetic Rh0-dimers, which contain two phosphinine-π-complexes acting as a bridging 2e--ligand towards the Rh2(CO)2 core. These compounds represent a missing coordination mode for the aromatic 6-membered… read more here.
Keywords: coordination mode; highly flexible; triaryl; missing coordination ... See more keywords
Changes in ligand coordination mode induce bimetallic C-C coupling pathways.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00322h
Abstract: Carbon-carbon coupling is one of the most powerful tools in the organic synthesis arsenal. Known methodologies primarily exploit monometallic Pd0/PdII catalytic mechanisms to give new C-C bonds. Bimetallic C-C coupling mechanisms that involve a PdI/PdII… read more here.
Keywords: ligand coordination; coordination; bimetallic coupling; changes ligand ... See more keywords
Coordination mode and stability of the tetrahydroborate ligand in group 10 metal pincer complexes.
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DOI: 10.1039/d2dt01357f
Abstract: The coordination mode of the BH4- ligand in transition metal tetrahydroborate complexes is mainly dominated by the nature of the metal centres. However, other factors can also play important roles sometimes. In order to rationalize… read more here.
Keywords: coordination; ligand; bh4; metal ... See more keywords
Synthesis, Characterization, and Reaction Studies of Pd(II) Tripeptide Complexes
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DOI: 10.3390/molecules26175169
Abstract: The aqueous synthesis of Pd(II) complexes with alkylated tripeptides led to the hydrolysis of the peptides at low pH values and mixtures of complexed peptides were formed. A non-aqueous synthetic route allowed the formation and… read more here.
Keywords: coordination; coordination mode; geometry; characterization reaction ... See more keywords