Seven new complexes based on various coordination modes of bifunctional ligand: Luminescent sensing and magnetic properties
Sign Up to like & getrecommendations! Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.118971
Abstract: Abstract Seven new complexes based on 4-(3-carboxyl-1,2,4-1H-triazol-1-yl)benzoic acid (H 2 L), namely [Zn(L)(H 2 O) 2 ] n ( 1 ), [Cd(L)(H 2 O) 2 ] n ( 2 ), [Pb(HL) 2 ] n (… read more here.
Keywords: coordination modes; bifunctional ligand; magnetic properties; new complexes ... See more keywords
The versatile coordination chemistry of 1,3-benzenedicarboxylate in the last 20 years: An investigation from the coordination modes to spectroscopic insights
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115068
Abstract: Abstract Aromatic carboxylates have been vastly applied as building blocks for the assembly of robust molecular-based materials owing to their potential application in various fields. In this family, 1,3-benzenedicarboxylate (1,3-bdc), which possesses a “V”-type configuration,… read more here.
Keywords: bdc; investigation; coordination chemistry; coordination modes ... See more keywords
Versatile Coordination Modes of Multidentate Neutral Amine Ligands with Group 1 Metal Cations
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.1c03786
Abstract: This work comprehensively investigated the coordination chemistry of a hexa-dentate neutral amine ligand, namely, N,N′,N”-tris-(2-N-diethylaminoethyl)-1,4,7-triaza-cyclononane (DETAN), with group-1 metal cations (Li+, Na+, K+, Rb+, Cs+). Versatile coordination modes were observed, from four-coordinate trigonal pyramidal to… read more here.
Keywords: neutral amine; coordination modes; coordination; chemistry ... See more keywords
Noncentrosymmetric versus Centrosymmetric: Halogen Induced Variable Coordination Modes of Sn2+ and Structural Transition in Sn3B3O7X (X = Cl and Br).
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c04255
Abstract: Two new borate halides, Sn3B3O7X (X = Cl and Br), were successfully synthesized via introducing Sn2+ with lone-pair and halogen into borate. Interestingly, halogen-induced variable coordination modes of Sn2+ and anion frameworks make them crystallize… read more here.
Keywords: halogen; coordination modes; induced variable; halogen induced ... See more keywords
Utility of Interchangeable Coordination Modes of N,N′-Dialkyl-2,6-pyridinediamide Tridentate Pincer Ligands for Solvent Extraction of Pd(II) and Zr(IV) from High-Level Radioactive Liquid Waste
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.4c03844
Abstract: A new class of ligands, N,N′-dialkyl-2,6-pyridinediamide (DRPDA), has been designed with the specific intention of exhibiting interchangeable diversity in coordination modes, including organometallic interactions, for the purpose of solvent extraction of elements relevant to the… read more here.
Keywords: chemistry; tridentate; dialkyl pyridinediamide; extraction ... See more keywords
Nonlinear Pathway for Remote Metal-Metal Communication in Heterobimetallic Complexes Enabled by Mixed NHC Ligands: Influence of Metal Coordination Modes.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c03237
Abstract: This work presents unique examples of two heterobimetallic complexes 4 and 5 that share the same overall molecular composition but display distinctly different electrochemical properties. These complexes were synthesized in high yields from an unsymmetrical… read more here.
Keywords: metal metal; heterobimetallic complexes; metal; communication ... See more keywords
New Coordination Modes for Modified Schiff Base Ti(IV) Complexes and Their Control over Lactone Ring-Opening Polymerization Activity.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b02271
Abstract: A series of eight new bis(alkoxy)bis(phenoxy-imine)titanium(IV) catalysts, coordinated by Schiff base ligands derived from o-vanillin (2-hydroxy-3-methoxybenzaldehyde), show good activity and control for the ring-opening polymerization of ε-caprolactone and ω-pentadecalactone. The new complexes are easily prepared… read more here.
Keywords: coordination; polymerization; coordination modes; type ... See more keywords
The influence of coordination modes and active sites of a 5-(triazol-1-yl) nicotinic ligand on the assembly of diverse MOFs.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01523b
Abstract: Six new complexes based on 5-(triazol-1-yl)nicotinic acid (HL), namely [Cu2(L)3(H2O)(OH)]n (1), [Co(L)2(H2O)2]n (2), [Mn(L)2(H2O)2]n (3), {[Co(L)(H2O)0.5(DMF)0.5(NO3)0.5]·(Cl)0.5·DMF·2H2O}n (4), {[Cu(L)(O)0.5]·CH3OH·2.5H2O}n (5) and {[Co2(L)4(H2O)]·2DMA·2H2O}n (6), were synthesized under hydro(solvo)thermal conditions. The L- ligand in 1-6 reveals various coordination… read more here.
Keywords: h2o h2o; triazol nicotinic; coordination modes; h2o ... See more keywords
Cooperative effects of metal cations and coordination modes on luminescent s-block metal–organic complexes constructed from V-shaped 4,4′-sulfonyldiphenol
Sign Up to like & getrecommendations! Published in 2018 at "CrystEngComm"
DOI: 10.1039/c8ce01591k
Abstract: The self-assembly of 4,4′-sulfonyldiphenol (H2sdp) with s-block metal salts in an aqueous or mixed H2O/alcohol solution gives rise to the formation of 13 new complexes, namely, [Li(Hsdp)(H2O)]n (1), [Na(Hsdp)(H2O)]n (2), [K(Hsdp)(H2sdp)(H2O)]n (3), [Cs(Hsdp)(solvent)(H2O)]n [solvent =… read more here.
Keywords: h2o; block metal; hsdp; coordination modes ... See more keywords
Ag7TaSe6: a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry C"
DOI: 10.1039/c9tc01587f
Abstract: A new noncentrosymmetric selenide exhibits fascinating “three in one” coordination modes and a strong second harmonic generation response. read more here.
Keywords: one coordination; coordination modes; three one; fascinating three ... See more keywords
Vinylimidazole coordination modes to Pt and Au metal centers
Sign Up to like & getrecommendations! Published in 2020 at "New Journal of Chemistry"
DOI: 10.1039/d0nj00845a
Abstract: The coordination modes of 1-vinylimidazole to platinum and gold were studied. Complexes [PtCl3(Hvinylimidazole)]·H2O (1), [Au(vinylimidazole)2]+[AuBr2]− (2), [Hvinylimidazole]+[AuCl4]− (3), and [Hvinylimidazole]+[AuBr4]− (4) were prepared and structurally characterized. Compound 1 is the first structurally characterized transition metal… read more here.
Keywords: coordination; modes metal; vinylimidazole coordination; chemistry ... See more keywords