Seven new complexes based on various coordination modes of bifunctional ligand: Luminescent sensing and magnetic properties
Sign Up to like & getrecommendations! Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.118971
Abstract: Abstract Seven new complexes based on 4-(3-carboxyl-1,2,4-1H-triazol-1-yl)benzoic acid (H 2 L), namely [Zn(L)(H 2 O) 2 ] n ( 1 ), [Cd(L)(H 2 O) 2 ] n ( 2 ), [Pb(HL) 2 ] n (… read more here.
Keywords: coordination modes; bifunctional ligand; magnetic properties; new complexes ... See more keywords
The versatile coordination chemistry of 1,3-benzenedicarboxylate in the last 20 years: An investigation from the coordination modes to spectroscopic insights
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115068
Abstract: Abstract Aromatic carboxylates have been vastly applied as building blocks for the assembly of robust molecular-based materials owing to their potential application in various fields. In this family, 1,3-benzenedicarboxylate (1,3-bdc), which possesses a “V”-type configuration,… read more here.
Keywords: bdc; investigation; coordination chemistry; coordination modes ... See more keywords
Versatile Coordination Modes of Multidentate Neutral Amine Ligands with Group 1 Metal Cations
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.1c03786
Abstract: This work comprehensively investigated the coordination chemistry of a hexa-dentate neutral amine ligand, namely, N,N′,N”-tris-(2-N-diethylaminoethyl)-1,4,7-triaza-cyclononane (DETAN), with group-1 metal cations (Li+, Na+, K+, Rb+, Cs+). Versatile coordination modes were observed, from four-coordinate trigonal pyramidal to… read more here.
Keywords: neutral amine; coordination modes; coordination; chemistry ... See more keywords
Noncentrosymmetric versus Centrosymmetric: Halogen Induced Variable Coordination Modes of Sn2+ and Structural Transition in Sn3B3O7X (X = Cl and Br).
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c04255
Abstract: Two new borate halides, Sn3B3O7X (X = Cl and Br), were successfully synthesized via introducing Sn2+ with lone-pair and halogen into borate. Interestingly, halogen-induced variable coordination modes of Sn2+ and anion frameworks make them crystallize… read more here.
Keywords: halogen; coordination modes; induced variable; halogen induced ... See more keywords
New Coordination Modes for Modified Schiff Base Ti(IV) Complexes and Their Control over Lactone Ring-Opening Polymerization Activity.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b02271
Abstract: A series of eight new bis(alkoxy)bis(phenoxy-imine)titanium(IV) catalysts, coordinated by Schiff base ligands derived from o-vanillin (2-hydroxy-3-methoxybenzaldehyde), show good activity and control for the ring-opening polymerization of ε-caprolactone and ω-pentadecalactone. The new complexes are easily prepared… read more here.
Keywords: coordination; polymerization; coordination modes; type ... See more keywords
The influence of coordination modes and active sites of a 5-(triazol-1-yl) nicotinic ligand on the assembly of diverse MOFs.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01523b
Abstract: Six new complexes based on 5-(triazol-1-yl)nicotinic acid (HL), namely [Cu2(L)3(H2O)(OH)]n (1), [Co(L)2(H2O)2]n (2), [Mn(L)2(H2O)2]n (3), {[Co(L)(H2O)0.5(DMF)0.5(NO3)0.5]·(Cl)0.5·DMF·2H2O}n (4), {[Cu(L)(O)0.5]·CH3OH·2.5H2O}n (5) and {[Co2(L)4(H2O)]·2DMA·2H2O}n (6), were synthesized under hydro(solvo)thermal conditions. The L- ligand in 1-6 reveals various coordination… read more here.
Keywords: h2o h2o; triazol nicotinic; coordination modes; h2o ... See more keywords
Cooperative effects of metal cations and coordination modes on luminescent s-block metal–organic complexes constructed from V-shaped 4,4′-sulfonyldiphenol
Sign Up to like & getrecommendations! Published in 2018 at "CrystEngComm"
DOI: 10.1039/c8ce01591k
Abstract: The self-assembly of 4,4′-sulfonyldiphenol (H2sdp) with s-block metal salts in an aqueous or mixed H2O/alcohol solution gives rise to the formation of 13 new complexes, namely, [Li(Hsdp)(H2O)]n (1), [Na(Hsdp)(H2O)]n (2), [K(Hsdp)(H2sdp)(H2O)]n (3), [Cs(Hsdp)(solvent)(H2O)]n [solvent =… read more here.
Keywords: h2o; block metal; hsdp; coordination modes ... See more keywords
Ag7TaSe6: a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry C"
DOI: 10.1039/c9tc01587f
Abstract: A new noncentrosymmetric selenide exhibits fascinating “three in one” coordination modes and a strong second harmonic generation response. read more here.
Keywords: one coordination; coordination modes; three one; fascinating three ... See more keywords
Vinylimidazole coordination modes to Pt and Au metal centers
Sign Up to like & getrecommendations! Published in 2020 at "New Journal of Chemistry"
DOI: 10.1039/d0nj00845a
Abstract: The coordination modes of 1-vinylimidazole to platinum and gold were studied. Complexes [PtCl3(Hvinylimidazole)]·H2O (1), [Au(vinylimidazole)2]+[AuBr2]− (2), [Hvinylimidazole]+[AuCl4]− (3), and [Hvinylimidazole]+[AuBr4]− (4) were prepared and structurally characterized. Compound 1 is the first structurally characterized transition metal… read more here.
Keywords: coordination; modes metal; vinylimidazole coordination; chemistry ... See more keywords
Hydrogen bonding promotes diversity in nitrite coordination modes at a single iron(II) center
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2020.1821373
Abstract: Abstract A low-valent [FeN5(OTf)2] complex and its bisnitrite adduct, [FeN5(NO2)2], have been synthesized in the interest of extending the reactivity of Fe complexes featuring redox-active ligands with secondary coordination sphere hydrogen-bond donors to nitrite reduction.… read more here.
Keywords: coordination; bonding promotes; coordination modes; nitrite ligands ... See more keywords