Selective adsorption of BTEX on calixarene-based molecular coordination network determined by 13C NMR spectroscopy
Sign Up to like & getrecommendations! Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.04.031
Abstract: Abstract Benzene, toluene, ethylbenzene, and xylenes (BTEX), a class of volatile organic compounds, are harmful pollutants but also very important precursors in organic industrial chemistry. Among different approaches used for the BTEX treatment, the adsorption… read more here.
Keywords: selective adsorption; spectroscopy; adsorption; coordination network ... See more keywords
Conductive Stimuli-Responsive Coordination Network Linked with Bismuth for Chemiresistive Gas Sensing.
Sign Up to like & getrecommendations! Published in 2021 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c14453
Abstract: This paper describes the design, synthesis, characterization, and performance of a novel semiconductive crystalline coordination network, synthesized using 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) ligands interconnected with bismuth ions, toward chemiresistive gas sensing. Bi(HHTP) exhibits two distinct structures upon… read more here.
Keywords: chemiresistive gas; spectroscopy; coordination network; network ... See more keywords
Flexible Coordination Network Exhibiting Water Vapor–Induced Reversible Switching between Closed and Open Phases
Sign Up to like & getrecommendations! Published in 2022 at "ACS Applied Materials & Interfaces"
DOI: 10.1021/acsami.2c10002
Abstract: That physisorbents can reduce the energy footprint of water vapor capture and release has attracted interest because of potential applications such as moisture harvesting, dehumidification, and heat pumps. In this context, sorbents exhibiting an S-shaped… read more here.
Keywords: water vapor; water; coordination network; hqs tmbp ... See more keywords
A novel 2D coordination network built from hexacopper(I)-iodide clusters and cagelike aminophosphine blocks for reversible “turn-on” sensing of aniline
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Materials Chemistry C"
DOI: 10.1039/c7tc03863a
Abstract: A new copper(I) coordination polymer [Cu6(μ3-I)6(μ3-PTAO)2]n (1) was prepared from copper(I) iodide and 1,3,5-triaza-7-phosphaadamantane-7-oxide (PTAO). The crystal structure of 1 reveals an intricate 2D coordination network constructed from the hexacopper(I)-iodide [Cu6(μ3-I)6] cluster units with the… read more here.
Keywords: coordination; paper; coordination network; topology ... See more keywords
Reversible single-crystal-to-single-crystal conversion of a photoreactive coordination network for rewritable optical memory storage.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/c9cc09081a
Abstract: Reversible single-crystal-to-single-crystal photocyclization-cycloreversion reaction of a stilbene-based coordination network exhibits a conspicuous fluorescence change. The controllable fluorescence and high fatigue resistance feature of this bistable material make it a single-crystalline device for applications in rewritable… read more here.
Keywords: rewritable optical; optical memory; single crystal; coordination network ... See more keywords
Acetylene storage performance of [Ni(4,4'-bipyridine)2(NCS)2]n, a switching square lattice coordination network.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06638b
Abstract: We report that the previously reported square lattice coordination network [Ni(4,4'-bipyridine)2(NCS)2]n, sql-1-Ni-NCS, undergoes acetylene induced switching between closed (nonporous) and open (porous) phases. The resulting stepped sorption isotherms exhibit temperature controlled steps, consistent high uptake… read more here.
Keywords: bipyridine ncs; acetylene storage; lattice coordination; square lattice ... See more keywords