Additive-Triggered Chain Transfer to a Solvent in Coordination Polymerization
Sign Up to like & getrecommendations! Published in 2020 at "Macromolecules"
DOI: 10.1021/acs.macromol.9b02495
Abstract: Low-molecular-weight polystyrene (LMPS) is the precursor of a brominated styrene oligomer that is used for small, precise, thin electrical components and an environmentally benign flame-retardant m... read more here.
Keywords: triggered chain; solvent coordination; coordination polymerization; transfer solvent ... See more keywords
Self-Activated Coordination Polymerization of Alkoxystyrenes by a Yttrium Precursor: Stereocontrol and Mechanism
Sign Up to like & getrecommendations! Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b00555
Abstract: Coordination–insertion polymerization of polar vinyl monomers has always been a challenging subject since the Lewis basic polar groups are usually poisonous to the Lewis acidic metal centers of the catalysts. In this paper, we report… read more here.
Keywords: self activated; polymerization; yttrium; coordination polymerization ... See more keywords
Light-mediated olefin coordination polymerization and photoswitches
Sign Up to like & getrecommendations! Published in 2020 at "Organic chemistry frontiers"
DOI: 10.1039/d0qo00426j
Abstract: Polyolefins are important polymeric materials in the plastics industry. While classical Ziegler–Natta catalysts are still superior in global polyolefin production, it is challenging to control their polymerization behavior due to intrinsic heterogeneity. A significant number… read more here.
Keywords: mediated olefin; coordination; polymerization; light mediated ... See more keywords
Coordination polymerization of nitrogen-rich linkers and dicyanamide anions toward energetic coordination polymers with low sensitivities.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt03180a
Abstract: The design and synthesis of energetic materials (EMs) with high energy and reliable stabilities has attracted much attention in the field of EMs. In this work, we employed a strategy of the coordination polymerization of… read more here.
Keywords: energetic coordination; coordination; coordination polymerization; dca mat ... See more keywords
DFT Modeling of Coordination Polymerization of Polar Olefin Monomers by Molecular Metal Complexes
Sign Up to like & getrecommendations! Published in 2024 at "Inorganics"
DOI: 10.3390/inorganics12090233
Abstract: Introducing polar functional groups into polyolefin chains through polar olefin monomer coordination (co)polymerization can directly and significantly improve the surface properties of polymer materials and expand their application range. Therefore, the related research has always… read more here.
Keywords: coordination polymerization; polar olefin; molecular metal; polymerization ... See more keywords
Statistical and Block Copolymers of n-Dodecyl and Allyl Isocyanate via Titanium-Mediated Coordination Polymerization: A Route to Polyisocyanates with Improved Thermal Stability
Sign Up to like & getrecommendations! Published in 2024 at "Polymers"
DOI: 10.3390/polym16243537
Abstract: Well-defined amorphous/semi-crystalline statistical copolymers of n-dodecyl isocyanate, DDIC, and allyl isocyanate, ALIC, were synthesized via coordination polymerization using the chiral half-titanocene complex CpTiCl2(O-(S)-2-Bu) as an initiator. In the frame of the terminal model, the monomer… read more here.
Keywords: block copolymers; thermal stability; polymerization; coordination polymerization ... See more keywords