Additive-Triggered Chain Transfer to a Solvent in Coordination Polymerization
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DOI: 10.1021/acs.macromol.9b02495
Abstract: Low-molecular-weight polystyrene (LMPS) is the precursor of a brominated styrene oligomer that is used for small, precise, thin electrical components and an environmentally benign flame-retardant m... read more here.
Keywords: triggered chain; solvent coordination; coordination polymerization; transfer solvent ... See more keywords
Self-Activated Coordination Polymerization of Alkoxystyrenes by a Yttrium Precursor: Stereocontrol and Mechanism
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DOI: 10.1021/acscatal.9b00555
Abstract: Coordination–insertion polymerization of polar vinyl monomers has always been a challenging subject since the Lewis basic polar groups are usually poisonous to the Lewis acidic metal centers of the catalysts. In this paper, we report… read more here.
Keywords: self activated; polymerization; yttrium; coordination polymerization ... See more keywords
Light-mediated olefin coordination polymerization and photoswitches
Sign Up to like & getrecommendations! Published in 2020 at "Organic chemistry frontiers"
DOI: 10.1039/d0qo00426j
Abstract: Polyolefins are important polymeric materials in the plastics industry. While classical Ziegler–Natta catalysts are still superior in global polyolefin production, it is challenging to control their polymerization behavior due to intrinsic heterogeneity. A significant number… read more here.
Keywords: mediated olefin; coordination; polymerization; light mediated ... See more keywords
Coordination polymerization of nitrogen-rich linkers and dicyanamide anions toward energetic coordination polymers with low sensitivities.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt03180a
Abstract: The design and synthesis of energetic materials (EMs) with high energy and reliable stabilities has attracted much attention in the field of EMs. In this work, we employed a strategy of the coordination polymerization of… read more here.
Keywords: energetic coordination; coordination; coordination polymerization; dca mat ... See more keywords