Enhanced photoelectrochemical hydrogenation of green-house gas CO2 to high-order solar fuel on coordinatively unsaturated metal-N sites containing carbonized Zn/Co ZIFs
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2019.06.102
Abstract: Abstract Porous carbon-based catalysts facilitate CO2 photoelectrochemical reduction reaction (CO2PRR) through the high charge transfer ability and CO2 adsorption ability. However, the design of catalysts with high selectivity towards high-order solar fuels (such as ethanol… read more here.
Keywords: order solar; order; unsaturated metal; coordinatively unsaturated ... See more keywords
The effect of oxygen vacancies on the coordinatively unsaturated Al-O acid-base pairs for propane dehydrogenation
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2021.03.033
Abstract: Abstract Recently, the coordinatively unsaturated metal-O Lewis acid−base pairs of metal oxides are found to be able to activate the C–H bond of light alkane efficiently. For the inert crystal Al2O3, we found that the… read more here.
Keywords: acid base; propane dehydrogenation; coordinatively unsaturated; oxygen ... See more keywords
Highly Efficient Visible-Light-Driven CO2-to-CO Conversion by Coordinatively Unsaturated Co-Salen Complexes in a Water-Containing System.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02515
Abstract: The development of cost-effective catalysts for CO2 reduction is highly desired but remains a significant challenge. The unsaturated coordination metal center in a catalyst is favorable for the process of catalytic CO2 reduction. In this… read more here.
Keywords: coordinatively unsaturated; unsaturated salen; salen; visible light ... See more keywords
Direct Observation of Coordinatively Unsaturated Sites on the Surface of a Fluoride-Doped Alumina Catalyst
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.7b02535
Abstract: Coordinatively unsaturated sites (CUS) present a key feature of alumina based catalysts as they are believed to act as Lewis-acid sites in heterogeneously catalyzed reactions. In the present study, the direct observation of active species… read more here.
Keywords: fluoride doped; unsaturated sites; direct observation; coordinatively unsaturated ... See more keywords
Improved Performance of g-C3N4 for Optoelectronic Detection of NO2 Gas by Coupling Metal-Organic Framework Nanosheets with Coordinatively Unsaturated Ni(II) Sites.
Sign Up to like & getrecommendations! Published in 2023 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.3c00903
Abstract: Sensitive and selective optoelectronic detection of NO2 with g-C3N4 (CN) is critical, but it remains challenging to achieve ultralow concentration (ppb-level) detection. Herein, Ni metal-organic frameworks/CN nanosheet heterojunctions were successfully fabricated by the electrostatic induced… read more here.
Keywords: unsaturated sites; coordinatively unsaturated; detection no2; metal organic ... See more keywords
Efficient catalysts of surface hydrophobic Cu-BTC with coordinatively unsaturated Cu(I) sites for the direct oxidation of methane.
Sign Up to like & getrecommendations! Published in 2023 at "Proceedings of the National Academy of Sciences of the United States of America"
DOI: 10.1073/pnas.2206619120
Abstract: Selective oxidation of methane to organic oxygenates over metal-organic frameworks (MOFs) catalysts at low temperature is a challenging topic in the field of C1 chemistry because of the inferior stability of MOFs. Modifying the surface… read more here.
Keywords: unsaturated sites; coordinatively unsaturated; oxidation methane; btc ... See more keywords
Synthesis of Coordinatively Unsaturated Iridium Complexes Having Functional 8-Quinolinolato Ligands: New Catalysts for Dehydrogenative Oxidation of Alcohols in Aqueous Media
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry Letters"
DOI: 10.1246/cl.170166
Abstract: New iridium complexes having functional 8-quinolinolato ligands have been synthesized. By single-crystal X-ray analysis, it was revealed that these new complexes had coordinatively unsaturated structure (five-coordinate trivalent iridium: 16e− complex). Furthermore, one of the new… read more here.
Keywords: iridium; complexes functional; quinolinolato ligands; functional quinolinolato ... See more keywords