Methylene-Bridged Bisphosphine Monoxide Ligands for Palladium-Catalyzed Copolymerization of Ethylene and Polar Monomers
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DOI: 10.1021/acsmacrolett.8b00034
Abstract: A series of palladium complexes bearing a bisphosphine monoxide with a methylene linker, that is, [κ2-P,O-(R12P)CH2P(O)R22]PdMe(2,6-lutidine)][BArF4] (Pd/BPMO), were synthesized and evaluated as catalysts for the homopolymerization of ethylene and the copolymerization of ethylene and polar… read more here.
Keywords: ethylene polar; polar monomers; copolymerization ethylene; copolymerization ... See more keywords
Dithiocarbamate-mediated controlled copolymerization of ethylene with cyclic ketene acetals towards polyethylene-based degradable copolymers
Sign Up to like & getrecommendations! Published in 2021 at "Polymer Chemistry"
DOI: 10.1039/d0py00200c
Abstract: In this article, degradable polyethylene (PE)-based copolymers containing ester units in the backbone were prepared through the hybrid copolymerization of ethylene and cyclic ketene acetals (CKAs) mediated by dithiocarbamate successfully. read more here.
Keywords: copolymerization ethylene; polyethylene based; ethylene cyclic; ketene acetals ... See more keywords
Copolymerization of Ethylene with Selected Vinyl Monomers Catalyzed by Group 4 Metal and Vanadium Complexes with Multidentate Ligands: A Short Review
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DOI: 10.3390/polym13244456
Abstract: This paper gives a short overview of homogeneous post-metallocene catalysts based on group 4 metal and vanadium complexes bearing multidentate ligands. It summarizes the catalytic behavior of those catalysts in copolymerization of ethylene with 1-olefins,… read more here.
Keywords: copolymerization ethylene; group metal; metal vanadium; vanadium complexes ... See more keywords
Recent Advances in the Copolymerization of Ethylene with Polar Comonomers by Nickel Catalysts
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DOI: 10.3390/polym14183809
Abstract: The less-expensive and earth-abundant nickel catalyst is highly promising in the copolymerization of ethylene with polar monomers and has thus attracted increasing attention in both industry and academia. Herein, we have summarized the recent advancements… read more here.
Keywords: nickel catalysts; advances copolymerization; copolymerization ethylene; copolymerization ... See more keywords