Copper/Bis(imine)‐Catalyzed Fluoroalkylative Thiocyanation of Unactivated Alkenes
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DOI: 10.1002/ejoc.202500393
Abstract: A method for the radical difunctionalization of non‐activated alkenes using fluorinated halides and thiocyanate anion is described. A combination of cheap copper(I) thiocyanate with a readily accessible bis(imine) ligand promoted the reaction under purple light… read more here.
Keywords: copper; imine catalyzed; bis imine; copper bis ... See more keywords
Copper bis-Dipyridoquinoxaline Is a Potent DNA Intercalator that Induces Superoxide-Mediated Cleavage via the Minor Groove
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DOI: 10.3390/molecules24234301
Abstract: Herein, we report the synthesis, characterisation, X-ray crystallography, and oxidative DNA binding interactions of the copper artificial metallo-nuclease [Cu(DPQ)2(NO3)](NO3), where DPQ = dipyrido[3,2-f:2′,3′-h]quinoxaline. The cation [Cu(DPQ)2]2+ (Cu-DPQ), is a high-affinity binder of duplex DNA and… read more here.
Keywords: copper bis; dpq; cleavage; dna ... See more keywords
Remote Steric Control of the Tetrahedral Coordination Geometry around Heteroleptic Copper(I) Bis(Diimine) Complexes
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DOI: 10.3390/molecules28030983
Abstract: In this study, a series of new heteroleptic copper(I) bis(diimine) complexes are described. Using one highly hindered phenanthroline ligand and a second less-hindered diimine ligand led to unexpected results. Following a two-step one-pot method to… read more here.
Keywords: copper; coordination; diimine; copper bis ... See more keywords