The first tris-heteroleptic copper cage, ligated by germsesquioxanes, 2,2′-bipyridines and 3,5-dimethylpyrazolates. Synthesis, structure and unique catalytic activity in oxidation of alkanes and alcohols with peroxides
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DOI: 10.1016/j.jorganchem.2019.120911
Abstract: Abstract Self-assembly reaction of copper(II) ions and triple set of ligands (phenylgermaniumsesquioxane, 2,2′-bipyridine, 3,5-dimethylpyrazolate) results in the formation of the first example of tris-heteroleptic copper cage product (PhGeO2)10Cu6(2,2′-bipy)2(3,5-Me2Pz)2 (1). The ligation styles of complex’ components… read more here.
Keywords: tris heteroleptic; copper; oxidation; heteroleptic copper ... See more keywords