Synthesis, Crystal Structure, and Catalytic Property of a Copper Coordination Compound Based on In Situ Generated 2-Hydroxynicotinic Acid
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Chemical Crystallography"
DOI: 10.1007/s10870-019-00818-0
Abstract: Abstract The copper coordination complex [CuCl(2-OHNA)H 2 O]·H 2 O ( 1 ) was synthesized by the reaction of CuCl 2 ·2H 2 O with in situ generated 2-hydroxynicotinic acid and its crystal structure was… read more here.
Keywords: generated hydroxynicotinic; copper coordination; situ generated; catalytic property ... See more keywords
Three-component synthesis of copper(ii) coordination compounds with 2-hetarylbenzothiazoles
Sign Up to like & getrecommendations! Published in 2019 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-019-2499-y
Abstract: A method for synthesizing CuII coordination compounds with 2-hetaryl-substituted benzothiazoles was developed. The reactions of 2-amino-5-methoxythiophenol, 2-pyridyl- or 2(4)-imidazolylcarbaldehydes, and copper(ii) perchlorate in refluxing ethanol yield L2Cu(ClO4)2 or L3Cu(ClO4)2 complexes. According to the cyclic voltammetry… read more here.
Keywords: coordination compounds; coordination; copper coordination; component synthesis ... See more keywords
Deciphering Copper Coordination in the Mammalian Prion Protein Amyloidogenic Domain.
Sign Up to like & getrecommendations! Published in 2020 at "Biophysical journal"
DOI: 10.1016/j.bpj.2019.12.025
Abstract: Prions are pathological isoforms of the cellular prion protein that is responsible for transmissible spongiform encephalopathies (TSE). Cellular prion protein interacts with copper, Cu(II), through octarepeat and nonoctarepeat (non-OR) binding sites. The molecular details of… read more here.
Keywords: coordination; prion; copper coordination; prion protein ... See more keywords
Synthesis, structural characterization and photoluminescent properties of copper(I) coordination polymers with extended C–H⋯π and CN⋯π interactions
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2016.10.012
Abstract: Abstract Two copper(I) coordination polymers, {[Cu 2 (pmb)(4,4′-bipyridine)(PPh 3 ) 2 ] (BF 4 ) 2 (CH 3 CN) 2 } n ( 1 ) and {[Cu 2 (pmb)(bpe)(PPh 3 ) 2 ](BF 4 )… read more here.
Keywords: nmr nmr; synthesis structural; copper coordination; coordination polymers ... See more keywords
Two Copper(II) coordination polymers constructed from 3,3-dimethylglutarate and citrate ligands
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.128695
Abstract: Abstract Two new Cu(II) coordination polymers, formulated as [Cu(μ4-dmg)(DMF)]n (1) and [Cu4(μ4-cit)2(H2O)8]n (2) (H2dmg = 3,3-dimethylglutaric acid and H4cit = citric acid) were successfully synthesized by using H2dmg and H4cit ligands under solvothermal conditions and characterized by single crystal… read more here.
Keywords: coordination; citrate; two copper; copper coordination ... See more keywords
Syntheses, structures and magnetic behaviors of 1D and 3D µ1,5-dicyanamide bridged copper(II) coordination polymers containing a symmetrical 1,2-diamine as a chelator
Sign Up to like & getrecommendations! Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2020.114693
Abstract: Abstract Two neutral copper(II) coordination polymers, [Cu(en)(µ1,5-dca)(dca)]n (1) and [Cu3(en)2(µ1,5-dca)6]n (2) [en = 1,2-ethanediamine, dca = dicyanamide], with µ1,5-dicyanamide bridges have been isolated. X-ray structural analysis reveals that each Cu(II) center in the asymmetric unit of 1 adopts a… read more here.
Keywords: dca; copper coordination; copper; geometry ... See more keywords
Multifunctional Copper(I) Coordination Polymers with Aromatic Mono- and Ditopic Thioamides.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b03364
Abstract: Direct reactions under ambient conditions between CuX (X = Br, I) and thiobenzamide (TBA) were carried out at different ratios, giving rise to the formation of a series of one-dimensional (1D) coordination polymers, (CPs) [CuI(TBA)]… read more here.
Keywords: tba; copper coordination; coordination polymers; multifunctional copper ... See more keywords
A series of five-coordinated copper coordination polymers for efficient degradation of organic dyes under visible light irradiation
Sign Up to like & getrecommendations! Published in 2017 at "RSC Advances"
DOI: 10.1039/c7ra03268d
Abstract: The copper(II) coordination polymers {[Cu4(OH)2(bix)2(1,2,4-btc)2(H2O)2]·3H2O}n (1), [Cu2(bix)(ip)2]n (2), [Cu2(bix)(Meip)2]n (3), {[Cu2(bix)(pbda)2]·H2O}n (4) and {[Cu2(bix)1.5(2,5-pydc)2(H2O)]·2H2O}n (5) were synthesized using the hydrothermal method (bix = 1,4-bis(2-methyl-imidazol-1-ylmethyl)benzene, 1,2,4-btc = 1,2,4-benzenetricarboxylate, ip = isophthalate, Meip = 5-methyl-isophthalate, pbda =… read more here.
Keywords: organic dyes; cu2; copper coordination; coordination polymers ... See more keywords
Chiral and achiral 1D copper(II) coordination polymers based on glycolato and chelating aromatic diamine ligands
Sign Up to like & getrecommendations! Published in 2018 at "CrystEngComm"
DOI: 10.1039/c8ce00279g
Abstract: Achiral glycolic acid and chelating aromatic diamine ligands were employed at room temperature to prepare five 1D copper(II) coordination polymers which were structurally characterized. The polymers ∞1{[Cu(HG)(dipyam)](HG)} (1) (dipyam = 2,2′-dipyridylamine) and ∞1[Cu(HG)(ClO4)(NN)] (NN =… read more here.
Keywords: chelating aromatic; copper coordination; coordination polymers; diamine ligands ... See more keywords
The Co2+/Ni2+ ion-mediated formation of a topochemically converted copper coordination polymer: structure-dependent electrocatalytic activity
Sign Up to like & getrecommendations! Published in 2019 at "CrystEngComm"
DOI: 10.1039/c9ce01178a
Abstract: The presence of Co2+/Ni2+ ions strongly influenced the formation of copper coordination polymers that showed a structure-dependent hydrogen evolution reaction catalytic activity. read more here.
Keywords: formation; co2 ni2; copper coordination; structure dependent ... See more keywords
A copper(II) coordination compound under water-oxidation reaction at neutral conditions: decomposition on the counter electrode.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01572b
Abstract: In the context of energy storage, the oxygen-evolution reaction (OER, 2H2O → O2 + 4H+ + 4e-) through the water-oxidation reaction is a thermodynamically uphill reaction in overall water splitting. In recent years, copper(II) coordination… read more here.
Keywords: reaction; coordination; water; coordination compound ... See more keywords