Solvent-Induced Spin-State Change in Copper Corroles.
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DOI: 10.1021/acs.inorgchem.2c02678
Abstract: The electronic structure of copper corroles has been a topic of debate and revision since the advent of corrole chemistry. The ground state of these compounds is best described as an antiferromagnetically coupled Cu(II) corrole… read more here.
Keywords: solvent induced; chemistry; copper corroles; spin state ... See more keywords
Ultrafast Dynamics and Strong Two-Photon Absorption Properties of Nonplanar β-Functionalized "Push-Pull" Copper Corroles with a Mixed Substituent Pattern.
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DOI: 10.1021/acs.inorgchem.2c03064
Abstract: A new series of nonplanar and unsymmetrically β-functionalized "push-pull" copper corroles, CuTPC(CHO)R7 [R = H, Br, Ph, Me, or 2-thienyl (Th)], were synthesized and characterized to elucidate the effect of β-functionalization and nonplanarity on the… read more here.
Keywords: photon absorption; copper corroles; two photon; cutpc cho ... See more keywords