An Artificial Metalloenzyme Based on a Copper Heteroscorpionate Enables sp3 C–H Functionalization via Intramolecular Carbene Insertion
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DOI: 10.1021/jacs.2c03311
Abstract: The selective functionalization of sp3 C–H bonds is a versatile tool for the diversification of organic compounds. Combining attractive features of homogeneous and enzymatic catalysts, artificial metalloenzymes offer an ideal means to selectively modify these… read more here.
Keywords: functionalization; copper heteroscorpionate; artificial metalloenzyme; metalloenzyme ... See more keywords