Revisiting Formal Copper(III) Complexes: Bridging Perspectives with Quasi‐d 10 Configurations
Sign Up to like & getrecommendations! Published in 2022 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202200247
Abstract: Abstract The formal Cu(III) complex [Cu(CF3)4]1− has often served as a paradigmatic example of challenging oxidation state assignment – with many reports proposing conflicting descriptions. Here we report a computational analysis of this compound, employing… read more here.
Keywords: formal copper; iii complexes; iii; revisiting formal ... See more keywords
The Myth of d8 Copper(III).
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b09016
Abstract: Seventeen Cu complexes with formal oxidation states ranging from CuI to CuIII are investigated through the use of multiedge X-ray absorption spectroscopy (XAS) and density functional theory (DFT) calculations. Analysis reveals that the metal-ligand bonding… read more here.
Keywords: formally cuiii; cuiii species; analysis; copper iii ... See more keywords