Investigating the Structure and Reactivity of Azolyl-Based Copper(I)–NHC Complexes: The Role of the Anionic Ligand
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DOI: 10.1021/acscatal.7b02737
Abstract: A family of copper(I)–NHC azolyl complexes was synthesized and deployed in the hydrosilylation of dicyclo-hexylketone to probe the role of the anionic ligand on catalytic performance. The azolyl ligand is shown to have a crucial… read more here.
Keywords: anionic ligand; role anionic; role; azolyl ... See more keywords
Mechanochemical solid state synthesis of copper(I)/NHC complexes with K3PO4
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DOI: 10.3762/bjoc.19.34
Abstract: A protocol for the mechanochemical synthesis of copper(I)/N-heterocyclic carbene complexes using cheap and readily available K3PO4 as base has been developed. This method employing a ball mill is amenable to typical simple copper(I)/NHC complexes but… read more here.
Keywords: synthesis copper; nhc complexes; copper; copper nhc ... See more keywords