Copper(II)-photocatalyzed decarboxylative oxygenation of carboxylic acids.
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DOI: 10.1039/d2cc00570k
Abstract: Showcasing the concept of light-induced homolysis for the generation of radicals, the CuII-photocatalyzed decarboxylative oxygenation of carboxylic acids with molecular oxygen as the terminal oxidant is described. Two CuII-carboxylate complexes with different coordination geometries were… read more here.
Keywords: oxygenation carboxylic; carboxylic acids; photocatalyzed decarboxylative; copper photocatalyzed ... See more keywords
Copper-photocatalyzed ATRA reactions: concepts, applications, and opportunities.
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DOI: 10.1039/d2cs00303a
Abstract: Atom transfer radical addition (ATRA) reactions are linchpin transformations in synthetic chemistry enabling the atom-economic difunctionalization of alkenes. Thereby a rich chemical space can be accessed through smart combinations of simple starting materials. Originally, these… read more here.
Keywords: applications opportunities; concepts applications; reactions concepts; atra reactions ... See more keywords