Nitrite Reduction by Trinuclear Copper Pyrazolate Complexes: An Example of a Catalytic, Synthetic Polynuclear NO Releasing System.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b00748
Abstract: Two trinuclear CuII pyrazolato complexes with a Cu3(μ3-E)-core (E = O2- or OH-) and terminal nitrite ligands in two coordination modes were characterized crystallographically, spectroscopically, and electrochemically. One-electron oxidation of the μ3-O species produces a… read more here.
Keywords: reduction; reduction trinuclear; trinuclear copper; pyrazolate complexes ... See more keywords
Trinuclear copper(II) pyrazolate compounds: a long story of serendipitous discoveries and rational design
Sign Up to like & getrecommendations! Published in 2017 at "CrystEngComm"
DOI: 10.1039/c7ce00009j
Abstract: In the past decade great effort has been put into the development of synthetic strategies to produce trinuclear triangular CuII (TTC) arrays, which may be synthetic analogues of the trinuclear site in ascorbate oxidase and… read more here.
Keywords: pyrazolate; compounds long; long story; trinuclear copper ... See more keywords