An Unrevealed Molecular Function of Corannulene Buckybowl Glycoconjugates in Selective Tumor Annihilation by Targeting the Cancer‐Specific Warburg Effect
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Science"
DOI: 10.1002/advs.202105315
Abstract: The biomedical application of corannulene π‐bowls is historically limited by low solubility and bioavailability despite the potential in their unique electronic properties for new functional materials. Herein, the unexpected role and molecular mechanism of Corranulene… read more here.
Keywords: selective tumor; warburg effect; corannulene; tumor ... See more keywords
Substituent effects on the electronic structures and nonlinear optical properties of Li-doped nano-carbon bowl
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Molecular Modeling"
DOI: 10.1007/s00894-017-3486-6
Abstract: A series of Li-corannulene-(NH2)n and Li-corannulene-(NO2)n (n = 1, 2, 5) compounds have been theoretically designed and investigated using density functional theory. In this work, two models are systematically investigated to explore the important factors for enhancing… read more here.
Keywords: corannulene nh2; nonlinear optical; corannulene; substitution group ... See more keywords
Corannulene: A Curved Polyarene Building Block for the Construction of Functional Materials.
Sign Up to like & getrecommendations! Published in 2021 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.1c00207
Abstract: ConspectusThis Account describes a body of research in the design and synthesis of molecular materials prepared from corannulene. Corannulene (C20H10) is a molecular bowl of carbon that can be visualized as the hydrogen-terminated cap of… read more here.
Keywords: block construction; corannulene; block; building block ... See more keywords
A curved host and second guest cooperatively inhibit the dynamic motion of corannulene
Sign Up to like & getrecommendations! Published in 2021 at "Nature Communications"
DOI: 10.1038/s41467-021-24344-w
Abstract: Biomolecular systems show how host–guest binding can induce changes in molecular behavior, which in turn impact the functions of the system. Here we report an artificial host–guest system where dynamic adaptation during guest binding alters… read more here.
Keywords: corannulene; second guest; guest; host second ... See more keywords
Effects of mPEG-DSPE/corannulene or perylene nanoparticles on the ovary and oocyte
Sign Up to like & getrecommendations! Published in 2020 at "RSC Advances"
DOI: 10.1039/d0ra02129f
Abstract: Corannulene (Cor) is a polycyclic aromatic hydrocarbon (PHA) whose molecular structure is three dimensional with a unique bowl-like structure and surface charge. Perylene (Per) is similar to corannulene, with 20π electrons in its fragrance system,… read more here.
Keywords: corannulene; perylene nanoparticles; dspe corannulene; corannulene perylene ... See more keywords
Flat corannulene: when a transition state becomes a stable molecule†
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc04566g
Abstract: Flat corannulene has been considered so far only as a transition state of the bowl-to-bowl inversion process. This study was driven by the prediction that substituents with strong steric repulsion could destabilize the bowl-shaped conformation… read more here.
Keywords: molecule; flat corannulene; corannulene; bowl ... See more keywords
A Diindole-fused Corannulene Imide Derivative: Synthesis and Properties
Sign Up to like & getrecommendations! Published in 2018 at "Chemistry Letters"
DOI: 10.1246/cl.180680
Abstract: A diindole-fused corannulene imide derivative was synthesized through two steps, Suzuki coupling and subsequent reductive cyclization reaction. Fusing indole rings to corannulene imide led to significantly red-shifted absorption, a lower HOMO–LUMO band gap, and a… read more here.
Keywords: corannulene; imide derivative; fused corannulene; corannulene imide ... See more keywords