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   Articles with "corrole" as a keyword



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Non-metallic Phosphorus Corrole Functioned as an Efficient Electrocatalyst in Hydrogen Evolution Reaction.

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recommendations! Published in 2022 at "ChemSusChem"

DOI: 10.1002/cssc.202201553

Abstract: The economical consideration of using an electrocatalyst in energy-related field, composed of non-precious/sustainable elements is quite noteworthy. In this work, the phosphorus (V) complex of tris-(pentafluorophenyl)corrole [ (TPFC)P V (OH) 2 ] was firstly reported… read more here.

Keywords: phosphorus; corrole; evolution reaction; hydrogen evolution ... See more keywords
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Synthesis, characterization, and reactivities of high valent metal–corrole (M = Cr, Mn, and Fe) complexes

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recommendations! Published in 2019 at "Coordination Chemistry Reviews"

DOI: 10.1016/j.ccr.2019.213043

Abstract: Abstract For the first-row middle transition metals (Cr, Mn, and Fe), the formal oxidation states are relatively lower. However, biological systems in various enzymatic reactions rely extensively on the higher oxidation states of these first-row… read more here.

Keywords: oxidation; higher oxidation; metal; high valent ... See more keywords

Ag(III)···Ag(III) Argentophilic Interaction in a Cofacial Corrole Dyad.

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recommendations! Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c02285

Abstract: Metallophilic interactions between closed-shell metal centers are exemplified by d10 ions, with Au(I) aurophilic interactions as the archetype. Such an interaction extends to d8 species, and examples involving Au(III) are prevalent. Conversely, Ag(III) argentophilic interactions… read more here.

Keywords: interaction; corrole; iii argentophilic; iii iii ... See more keywords
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On-Surface Synthesis and Characterization of an Iron Corrole

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recommendations! Published in 2018 at "Journal of Physical Chemistry C"

DOI: 10.1021/acs.jpcc.8b00067

Abstract: To explore the possibility of tuning the oxidation state of a coordinated metal ion in an adsorbed tetrapyrrole complex by a minor modification of the ligand structure, multilayers and monolayers of 3H-hexaethyl-dimethyl-corrole (3H-HEDMC) on Ag(111)… read more here.

Keywords: surface synthesis; spectroscopy; iron corrole; corrole ... See more keywords
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Protein-coated corrole nanoparticles for the treatment of prostate cancer cells.

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recommendations! Published in 2020 at "Cell death discovery"

DOI: 10.1038/s41420-020-0288-x

Abstract: Development of novel therapeutic strategies to eradicate malignant tumors is of paramount importance in cancer research. In a recent study, we have introduced a facile protocol for the preparation of corrole-protein nanoparticles (NPs). These NPs… read more here.

Keywords: protein; prostate cancer; cancer; corrole ... See more keywords
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Positive shift in corrole redox potentials leveraged by modest β-CF3-substitution helps achieve efficient photocatalytic C-H bond functionalization by group 13 complexes.

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recommendations! Published in 2019 at "Dalton transactions"

DOI: 10.1039/c9dt02150g

Abstract: Tris- and tetrakis-β-trifluoromethylated gallium (3CF3-Ga, 4CF3-Ga) and aluminum (3CF3-Al, 4CF3-Al) corrole systems were synthesized by a facile "one-pot" approach from the respective tri- and tetra-iodo starting compounds using the FSO2CF2CO2Me reagent. The isolated 5,10,15-(tris-pentafluorophenyl)corrole-based compounds… read more here.

Keywords: cf3; group; substitution; positive shift ... See more keywords
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Copper corrole immobilized onto reduced graphene oxide: An efficient electrocatalyst for hydrogen evolution reaction

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recommendations! Published in 2023 at "Journal of Porphyrins and Phthalocyanines"

DOI: 10.1142/s1088424623500682

Abstract: First-row transition metal complexes derived from corrole-based ligands are considered efficient catalysts for hydrogen evolution reaction (HER). They are known to enhance the rate of hydrogen production by lowering the energy barrier in the water-splitting… read more here.

Keywords: corrole; graphene oxide; reduced graphene; evolution reaction ... See more keywords