Grignard Reagent Mediated Demetallation of Silver Corrole Complexes
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201601549
Abstract: Abstract: In order to study the reactivity of various Grignard reagents with differently substituted A3− and trans-A2B-corrolato Ag (III) complexes, we have performed a series of reactions. We have observed that among the various Grignard… read more here.
Keywords: silver corrole; reagent mediated; demetallation silver; mediated demetallation ... See more keywords
Catalytic Preparation of Cyclic Carbonates from CO2 and Epoxides by Metal–Porphyrin and −Corrole Complexes: Insight into Effects of Cocatalyst and meso-Substitution
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00830
Abstract: Extensive DFT calculations have been performed to elucidate the plausible mechanisms and effects of the cocatalyst and meso-substitution of the macro ring on the coupling reaction of CO2 with epoxide catalyzed by metal prophyrin and… read more here.
Keywords: meso substitution; cocatalyst meso; corrole complexes; effects cocatalyst ... See more keywords
Bridging and axial carbene binding modes in cobalt corrole complexes: effect on carbene transfer.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc07073d
Abstract: Catalytically relevant intermediates in carbene transfer reactions from a diazo precursor were investigated using cobalt corrole complexes. Two divergent mechanisms are proposed depending on the oxidation state of the cobalt center. Mechanistically driven factors for… read more here.
Keywords: cobalt corrole; carbene transfer; carbene; corrole complexes ... See more keywords