Counter Cations Affect Transport in Aqueous Hydroxide Solutions with Ion Specificity.
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DOI: 10.1021/jacs.8b13458
Abstract: The anomalously high mobility of hydroxide and hydronium ions in aqueous solutions is related to proton transfer and structural diffusion. The role of counterions in these solutions, however, is often considered to be negligible. Herein,… read more here.
Keywords: transport aqueous; aqueous hydroxide; affect transport; cations affect ... See more keywords
Cation-based Structural Tuning of Pyridine Dipyrrolate Cages and Morphological Control over Their Self-assembly.
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DOI: 10.1021/jacs.9b01042
Abstract: Different pyridine dipyrrolate cages including cage-based dimers and polymers may be fabricated in a controlled manner from the same two starting materials, namely, an angular ligand 1 and Zn(acac)2, by changing the counter cation source.… read more here.
Keywords: cation; counter cations; pyridine dipyrrolate; cation based ... See more keywords
Unraveling the role of counter-cations in Pd-catalyzed carboxylic acid C–H activation
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DOI: 10.1039/d5sc06297g
Abstract: The counter-cation effect has been proved by experiments to be very crucial in the Pd-catalyzed C–H activation of carboxylic acid but its mechanism is still unclear. In this study, the reaction mechanism of the Pd-catalyzed… read more here.
Keywords: counter; role; counter cations; palladium species ... See more keywords