Photoinduced Cation Coupled Electron Transfer for Efficient Ionic Power Harvesting Based on CNT/MoS2 Heterostructures
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Materials"
DOI: 10.1002/adma.202508641
Abstract: Inspired from the light‐driven proton‐coupled electron transfer during photosynthesis in green plants, an engineered CNT/MoS2 biomimetic nanofluidic system has been successfully developed, which achieves photo‐activated ion transport in iso‐concentration electrolytes through synergistic photothermal‐photoelectric coupling. Under… read more here.
Keywords: efficient ionic; electron transfer; coupled electron; transfer ... See more keywords
Effect of Anchoring Dynamics on Proton-Coupled Electron Transfer in the Ru(bda) Coordination Oligomer on a Graphitic Surface.
Sign Up to like & getrecommendations! Published in 2024 at "ChemPlusChem"
DOI: 10.1002/cplu.202400082
Abstract: The oligomeric ruthenium-based water oxidation catalyst, Ru(bda), is known to be experimentally anchored on graphitic surfaces through CH-π stacking interactions between the auxiliary bda ([2,2'-bipyridine]-6,6'-dicarboxylate) ligand bonded to ruthenium and the hexagonal rings of the… read more here.
Keywords: electron transfer; coupled electron; proton coupled; graphitic surface ... See more keywords
Photoelectrochemical C-H Activation Through a Quinacridone Dye Enabling Proton-Coupled Electron Transfer.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202201980
Abstract: Dye-sensitized photoanodes for C-H activation in organic substrates are assembled by vacuum sublimation of a commercially available quinacridone (QNC) dye in the form of nanosized rods onto fluorine-doped tin oxide (FTO), TiO2 , and SnO2… read more here.
Keywords: coupled electron; electron transfer; proton coupled; quinacridone ... See more keywords
Photocatalytic Nitrate Reduction to Ammonia via Zr‐Mediated Proton‐Coupled Electron Transfer
Sign Up to like & getrecommendations! Published in 2025 at "Chemsuschem"
DOI: 10.1002/cssc.202402630
Abstract: Abstract The reduction of nitrate (NO3 −) is a fundamentally exciting reaction with important environmental implications. From a mechanistic perspective, it involves the transfer of 8 e− and 9 H+, with the initial activation of NO3… read more here.
Keywords: proton coupled; electron transfer; nitrate; coupled electron ... See more keywords
Enhanced Photocatalytic Proton‐Coupled Electron Transfer by Ligand Design in a Zr Coordination Cage
Sign Up to like & getrecommendations! Published in 2025 at "Chemsuschem"
DOI: 10.1002/cssc.202500219
Abstract: Abstract Developing excited state proton and electron donors is a promising area of research that merges the benefits of proton‐coupled electron transfer (PCET) with the use of light as renewable energy input. Based on the… read more here.
Keywords: proton coupled; proton; electron transfer; cage ... See more keywords
Voltammetric applications of hydrogen bonding and proton-coupled electron transfer reactions of organic molecules
Sign Up to like & getrecommendations! Published in 2019 at "Current Opinion in Electrochemistry"
DOI: 10.1016/j.coelec.2019.03.013
Abstract: Abstract Proton-coupled electron transfer and hydrogen bonding reactions are ubiquitous requisites for the occurrence of many natural processes and man-made applications. These reactions either involve the direct transfer of charge (in the form of protons… read more here.
Keywords: transfer; coupled electron; proton coupled; electron transfer ... See more keywords
Theory on optimizing the activity of electrocatalytic proton coupled electron transfer reactions
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2019.06.037
Abstract: Abstract Understanding the effects of pH and potential on proton-coupled electron transfer (PCET) steps and optimizing the reaction activity are of key importance for efficient applications of energy conversion processes. In this work, we develop… read more here.
Keywords: activity; proton; transfer; coupled electron ... See more keywords
Theoretical Modeling of Electrochemical Proton-Coupled Electron Transfer.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.1c00929
Abstract: Proton-coupled electron transfer (PCET) plays an essential role in a wide range of electrocatalytic processes. A vast array of theoretical and computational methods have been developed to study electrochemical PCET. These methods can be used… read more here.
Keywords: coupled electron; proton; electron transfer; proton coupled ... See more keywords
Involvement of a Formally Copper(III) Nitrite Complex in Proton-Coupled Electron Transfer and Nitration of Phenols.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03790
Abstract: A unique high-valent copper nitrite species, LCuNO2, was accessed via the reversible one-electron oxidation of [M][LCuNO2] (M = NBu4+ or PPN+). The complex LCuNO2 reacts with 2,4,6-tri-tert-butylphenol via a typical proton-coupled electron transfer (PCET) to… read more here.
Keywords: electron transfer; proton coupled; electron; coupled electron ... See more keywords
Connecting Thermodynamics and Kinetics of Proton Coupled Electron Transfer at Polyoxovanadate Surfaces Using the Marcus Cross Relation
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c02541
Abstract: Here, we evaluate the efficacy of multiple methods for elucidating the average bond dissociation free energy (BDFE) of two surface hydroxide moieties in a reduced polyoxovanadate cluster, [V6O11(OH)2(TRIOLNO2)2]−2. Through cyclic voltammetry, individual thermochemical parameters describing… read more here.
Keywords: transfer; coupled electron; thermodynamics; electron transfer ... See more keywords
Proton-Coupled Electron Transfer between a Pendant Thiol and a Ferrous Dioxygen Adduct.
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.4c03802
Abstract: The mechanism of thiol oxidation by O2, as catalyzed by ferrous porphyrins, is investigated by trapping intermediates of the transformation at low temperatures and subsequently characterizing them using continuous wave and pulsed electron paramagnetic resonance… read more here.
Keywords: pendant thiol; coupled electron; proton coupled; electron transfer ... See more keywords